Synthesis and Biological Activity of Novel Anthranilic Diamide Derivatives Containing 1,2,4-Triazole Schiff Base

doi:10.3724/SP.J.1095.2014.40035

Chinese Journal of Applied Chemistry

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Synthesis and Biological Activity of Novel Anthranilic Diamide Derivatives Containing 1,2,4-Triazole Schiff Base

ZHENG Yuguo^*, SONG Zebin, SONG Song, LI Zhongming, DENG Zhao, WU Yong, FU Rukai, HUANG Yong, GUO Qingqing

(Key Laboratory of Research and Development of Ethnomedicinal Biological Resources,Institute of Green
Chemistry-Synthesis Technology,Xingyi Normal University for Nationalities,Xingyi 562400,China)

Received:2014-02-03 Revised:2014-04-21 Published:2014-10-09 Online:2014-10-09
Contact: Zheng Yuguo

Abstract

Abstract: Using 2,4-dichlorobenzoic acid and 2-amino-3-methylbenzoic acid as starting materials, eight novel anthranilic diamide derivatives containing 1,2,4-triazole Schiff base and 2,4-dichlorophenyl unit were synthesized. The structures were confirmed by 1H NMR, IR and elemental analysis. The preliminary bioassay showed that compound 9a has significant insecticidal activity with 100% inhibition of Leucania separata and Plutella xylostella at 600 mg/L.

Key words: anthranilic diamide, dichlorophenyl, triazole, synthesis, biological activity

CLC Number:

O626.2

ZHENG Yuguo*, SONG Zebin, SONG Song, LI Zhongming, DENG Zhao, WU Yong, FU Rukai, HUANG Yong, GUO Qingqing. Synthesis and Biological Activity of Novel Anthranilic Diamide Derivatives Containing 1,2,4-Triazole Schiff Base[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.40035.

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Synthesis and Biological Activity of Novel Anthranilic Diamide Derivatives Containing 1,2,4-Triazole Schiff Base

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