Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide

doi:10.3724/SP.J.1095.2014.30599

Chinese Journal of Applied Chemistry

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Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide

ZENG Yanfei, ZHOU Yuanlin^*

(State Key Laboratory Cultivation Base for Nonmetal Composite and Functional Materials；
School of Materials Science and Engineering，
Southwest University of Science and Technology，Mianyang 621010，China)

Received:2013-11-27 Revised:2014-04-16 Published:2014-09-03 Online:2014-09-03
Contact: yuanlin zhou

Abstract

Abstract: Sodium n-butylxanthate obtained from n-butyl alcohol, sodium hydroxide and carbon disulfide in water was converted to symmetrical dibutyl xanthate disulfide by reacting with disulfur dichloride(S2Cl2) at room temperature. The effects of reaction conditions on the yields of the sodium nbutylxanthate and dibutyl xanthate disulfide were investigated respectively. Characterizations of dibutyl xanthate disulfide were done using Fourier transform infrared(FT-IR) spectroscopy, 1H nuclear magnetic resonance(1H NMR）spectroscopy, mass spectroscopy(MS) and elemental analysis techniques. In optimized reaction conditions, the molar ratio of sodium n-butylxanthate to S2Cl2 is 1∶1.1 in THF solvent. The reaction completes within 2 min at room temperature to give up to 83.2% yield.

Key words: sodium n-butyxanthate, dibutyl xanthate disulfide, accelerant, synthesis, structure characterization

CLC Number:

O621

ZENG Yanfei, ZHOU Yuanlin*. Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30599.

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Room Temperature Synthesis and Characterization of Dibutyl Xanthate Disulfide

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