Using 2-Thiobarbituric Acid-modified Gold Nanoparticles as Colorimetric Probes for Sensitive Detection of Melamine

doi:10.3724/SP.J.1095.2014.30249

Chinese Journal of Applied Chemistry

• Full Papers • Previous Articles Next Articles

Using 2-Thiobarbituric Acid-modified Gold Nanoparticles as Colorimetric Probes for Sensitive Detection of Melamine

FEI Yao¹, GUO Han², XI Huanxiang¹, CHEN Wanyi¹, CAI Linyi¹, WANG Aijun¹, FENG Jiuju^1,2*

(1.College of Chemistry and Life Science,Zhejiang Normal University,Jinhua 321004,China;
2.School of Chemistry and Chemical Engineering,Henan Normal University,Xinxiang 453007,China)

Received:2013-05-20 Revised:2013-06-17 Published:2014-04-10 Online:2014-04-10

Abstract

Abstract: A simple and rapid colorimetric method was developed for the detection of melamine using 2-thiobarbituric acid-modified gold nanoparticles(TBA-AuNPs) as probes. Melamine can induce the aggregation of TBA-AuNPs via the hydrogen-bonding interactions in acetic acid buffer solutions(pH=7), resulting in the color change from wine-red to blue within 15 min at room temperature. Under optimized conditions, the absorption ratio of the A660/A520 shows good linear relationship with the melamine concentration in the range of 0.062~0.18 μmol/L and 0.18~6.0 μmol/L, respectively, with the detection limit of 0.043 μmol/L. The recoveries of the method are within the range of 102.8%～105.3%. It provides a platform for rapid, selective and sensitive colorimetric detection of melamine in milk samples.

Key words: melamine, thiobarbituric acid, gold nanoparticles probes, colorimetric method

CLC Number:

O657.3

FEI Yao1, GUO Han2, XI Huanxiang1, CHEN Wanyi1, CAI Linyi1, WANG Aijun1, FENG Jiuju1,2*. Using 2-Thiobarbituric Acid-modified Gold Nanoparticles as Colorimetric Probes for Sensitive Detection of Melamine[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30249.

References

[1] Brown C A,Jeong K S,Poppenga R H,et al. Outbreaks of Renal Failure Associated with Melamine and Cyanuric Acid in Dogs and Cats in 2004 and 2007[J]. J Vet Diagn Invest,2007,19(5):525-531.

[2] Ibanez M,Sancho J V,Hernandez F. Determination of Melamine in Milk-Based Products and Other Food and Beverage Products by Ion-Pair Liquid Chromatography-Tandem Mass Spectrometry[J]. Anal Chim Acta,2009,649(1):91-97.

[3] Li J,Qi H Y,Shi Y P. Determination of Melamine Residues in Milk Products by Zirconia Hollow Fiber Sorptive Microextraction and Gas Chromatography-Mass Spectrometry[J]. J Chromatogr A,2009,1216(29):5467-5471.

[4] Klampfl C W,Andersen L,Haunschmidt M,et al. Analysis of Melamine in Milk Powder by Cze Using UV Detection and Hyphenation with ESI Quadrupole/TOF MS Detection[J]. Electrophoresis,2009,30(10):1743-1746.

[5] Tsai I L,Sun S W,Liao H W,et al. Rapid Analysis of Melamine in Infant Formula by Sweeping-Micellar Electrokinetic Chromatography[J]. J Chromatogr A,2009,1216(47):8296-8303.

[6] Liu D,Wang Z,Jiang X. Gold Nanoparticles for the Colorimetric and Fluorescent Detection of Ions and Small Organic Molecules[J]. Nanosclae,2011,3(4):1421-1433.

[7] Vilela D,Gonzalez M C,Escarpa A. Sensing Colorimetric Approaches Based on Gold and Silver Nanoparticles Aggregation:Chemical Creativity Behind The Assay[J]. Anal Chim Acta,2012,751:24-43.

[8] Ai K,Liu Y,Lu L. Hydrogen-Bonding Recognition-Induced Color Change of Gold Nanoparticles for Visual Detection of Melamine in Raw Milk and Infant Formula[J]. J Am Chem Soc,2009,131(27):9496-9497.

[9] Liang X S ,Wei H P,Cui Z Q,et al. Colorimetric Detection of Melamine in Complex Matrices Based on Cysteamine-Modified Gold Nanoparticles[J]. Analyst,2011,136(1):179-183.

[10] Wu Z,Zhao H,Xue Y,et al. Colorimetric Detection of Melamine During the Formation of Gold Nanoparticles[J]. Biosens Bioelectron,2011,26(5):2574-2578.

[11] Li L,Li B X,Cheng D,et al. Visual Detection of Melamine in Raw Milk Using Gold Nanoparticles as Colorimetric Probe[J]. Food Chem,2010,122(3):895-900.

[12] SUN Chunyan，ZHANG Minwei，LI Hongkun，et al. Gold Nanoparticles-based Colorimetric Sensing of Melamine in Milk and Eggs[J]. Chinese J Anal Chem,2012,40(3):386-390(in Chinese).

孙春燕,张民伟,李宏坤,等. 金纳米粒比色探针测牛奶及鸡蛋中的三聚氰胺[J]. 分析化学,2012,40(3):386-390.

[13] Chen W,Deng H H,Hong L,et al. Bare Gold Nanoparticles as Facile and Sensitive Colorimetric Probe for Melamine Detection[J]. Analyst,2012,137(22):5382-5386.

[14] Cao Q,Zhao H,He Y,et al. Hydrogen-bonding-induced Colorimetric Detection of Melamine by Nonaggregation-based Au-NPs as a Probe[J]. Biosens Bioelectron,2010,25(12):2680-2685.

Using 2-Thiobarbituric Acid-modified Gold Nanoparticles as Colorimetric Probes for Sensitive Detection of Melamine

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 9

Recommended Articles

Metrics

Comments

[1]	Xiao-Mei WANG, Jiang-Fei GUO, Li-Zhi WANG, Jian-Han HUANG. Porphyrin⁃Based Hyper⁃cross⁃Linked Polymer： Preparation and Adsorption of Carbon Dioxide and Hg（Ⅱ） Ion [J]. Chinese Journal of Applied Chemistry, 2022, 39(7): 1083-1089.
[2]	LIU Minghui, LIU Yingcen, Lü Rongwen. Preparation of Carbon-Supported Highly Dispersed Palladium Nanoparticles and Their Performance for Suzuki Reaction [J]. Chinese Journal of Applied Chemistry, 2020, 37(1): 61-68.
[3]	ZHU Deqin, SHENG Yu, ZHENG Shouyang, TONG Qingsong. Effect of the Melamine Polyphosphate/Pentaerythritol Ratio, Synergist Group and Surface Modification on Intumescent Flame Retardants of Polypropylene- Based Wood-Plastic Composites [J]. Chinese Journal of Applied Chemistry, 2019, 36(6): 649-657.
[4]	LIN Qiang, GUO Shuyi, HUANG Yiping, XU Gewen, BAO Junjie, CHENG Qin. Preparation and Charaterization of Hexakis(methoxymethyl)melamine Crosslinking Waterborne Polyurethane [J]. Chinese Journal of Applied Chemistry, 2016, 33(10): 1154-1160.
[5]	MA Qian,LIU Zengjie,LIANG Yi,DONG Tianhe,HAN Fuqin. Encapsulated Red Phosphorus in Dihydric Alcohol Modified Melamine Formaldehyde Resin [J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1153-1158.
[6]	XU Siyuan, LEI Ping, JIN Guanping*. Determination of Pb(Ⅱ), Cd(Ⅱ) with Melamine Chelating Resin/Multi-walled Carbon Nanotubes Composites Modified Waxed Graphite Electrode [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 206-211.
[7]	LIU Yunan1,2, ZHANG Zhaohui1,2,3*, CHEN Xing1, CHEN Hongjun1, RAO Wei1, CAI Rong1. Preparation and Application of Melamine Magnetic Molecularly Imprinted Solid Phase Extraction Material [J]. Chinese Journal of Applied Chemistry, 2013, 30(10): 1222-1230.
[8]	ZHANG Yi1, HAN Xiaoyan2*, ZHAO Peili1, GUO Weiyi2, ZHANG Zhengpu3. Adsorbent Preconcentration by PTFE-g-GMA-SO3H Fiber Coupled with HPLC for Determination of Trace Melamine in Milk Preparations [J]. Chinese Journal of Applied Chemistry, 2011, 28(04): 448-453.
[9]	Zhang Guanghua, Zhang Xinghua. ON THE SINGLE CRYSTAL IN MF/PVA COMPOSITES [J]. Chinese Journal of Applied Chemistry, 1993, 0(1): 95-97.