Preparation of Dodecyl Sulfonate-Layered Double Hydroxides and Influence on Nicosulfuron Oil Flowable Concentrate Rheological Property

doi:10.3724/SP.J.1095.2013.20560

Chinese Journal of Applied Chemistry

• Full Papers • Previous Articles Next Articles

Preparation of Dodecyl Sulfonate-Layered Double Hydroxides and Influence on Nicosulfuron Oil Flowable Concentrate Rheological Property

ZHAI Lili¹, LU Fusui^2*, XIA Hui¹, LIAO Kechao¹

(1.College of Plant Protection;2.College of Chemistry and Materials Science,
Shandong Agricultural University,Tai′an 271018,China)

Received:2012-12-03 Revised:2013-01-17 Published:2013-10-10 Online:2013-10-10
Contact: LU Fusui

Abstract

Abstract: Hydrophobic dodecyl sulfonate-layered double hydroxides（DSO-LDHs） were prepared with Mg-Al-LDHs as the precursors, and its structure was characterized by XRD, optical microscope and FTIR. The results indicate that DSO anions are intercalated into LDHs interlayer successfully. In this paper, DSO-LDHs were applied as thixotropic materials in 4% nicosulfuron oil flowable suspension. The rheological results indicate that pesticide particles are attached to DSO-LDHs through electrostatic interaction since DSO-LDHs has a special structure of hydrotalcite laminated layers. As the concentration of DSO-LDHs increases, the oil suspension shows a positive thixotropy, and the yield value is also increased, whereas the oil separation ratio is decreased.

CLC Number:

O648

ZHAI Lili1, LU Fusui2*, XIA Hui1, LIAO Kechao1. Preparation of Dodecyl Sulfonate-Layered Double Hydroxides and Influence on Nicosulfuron Oil Flowable Concentrate Rheological Property[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2013.20560.

References

[1] DAI Quan. Development and Research of Vegetable Oil Flowable Concentrate[J]. Anhui Chem Ind,2006,（2）:50-51(in Chinese).

戴权. 植物油悬浮剂的研究与开发[J]. 安徽化工,2006,（2）:50-51.

[2] BU Xiaoli,HUANG Qiliang,WANG Guoping,et al. Prospects for Utilizing Thixotropy in Pesticide Suspension Systems[J]. Agrochemicals,2006,45(4):231-236(in Chinese).

卜小莉,黄啟良,王国平,等. 触变性及其在农药悬浮体系中的应用前景[J]. 农药,2006,45(4):231-236.

[3] NIU Xiangnan,HONG Tao. Synthesis Methods and Application of Layered Double Hydroxides in Water Pollution Control[J]. Chem Eng,2010，(1):27-28,49(in Chinese).

牛向楠,洪涛. 水滑石类材料的制备及在水污染治理中的应用[J]. 化学工程师,2010，(1):27-28,49.

[4] YU Weihua,TONG Dongshen,ZHOU Chunhui,et al. Quality Analysis and Application of Hydrotalcite-like Compounds[J]. China Non-metallic Mining Ind Herald,2012,(2):47-50(in Chinese).

俞卫华,童东绅,周春晖,等. 类水滑石矿物的产品分析与应用[J]. 中国非金属矿工业导刊,2012,(2):47-50.

[5] Costantino U,Ambrogi V,Nocchetti M,et al. Hydrotalcite-like Compounds:Versatile Layered Hosts of Molecular Anions with Biological Activity[J]. Micropor Mesopor Mater,2008,107(1/2):149-160.

[6] Aschenbrenner O,McGuire P,Alsamaq S,et al. Adsorption of Carbon Dioxide on Hydrotalcite-like Compounds of Different Compositions[J]. Chem Eng Res Design,2011,89(9):1711-1721.

[7] ZHANG Yunbo,HOU Wanguo,WANG Wenxing. Adsorption-desorption of Chromium(Ⅵ) on Mg-Al Hydrotalcite-like Compounds:Part I Adsorption[J]. Acta Chim Sin,2007,65(9):773-778(in Chinese).

臧运波,侯万国,王文兴. Cr(Ⅳ)在Mg-Al型类水滑石上的吸附-脱附性研究:Ⅰ.吸附性[J]. 化学学报,2007,65(9):773-778.

[8] Dimetakis E D,Pinnavaia T J. New Route to Layered Double Hydroxides Intercalated by Organic Anions:Precursors to Polyoxometalate-pillared Derivatives[J]. Inorg Chem,1990,29(13):2393-2394.

[9] KE Yangchuan,WEI Guangyao. Application and Development of Nanomaterials in Oil Drilling and Recovery[J]. Oilfield Chem,2008,25(2):189-192(in Chinese).

柯扬船,魏光耀. 纳米材料在石油天然气田开发中的应用进展[J]. 油田化学,2008,25(2):189-192.

[10] CHEN Tiantian,LU Fusui,LI Xianwei,et al. Influence of Mg-Al MMH on the Rheology of Diflubenzuron SC[J]. Chem J Chinese Univ,2010,31(10):2036-2041(in Chinese).

陈甜甜,路福绥,李现伟,等. Mg-Al MMH对除虫脲水悬浮剂流变性的影响[J]. 高等学校化学学报,2010,31(10):2036-2041.

[11] LI Dianqing,FENG Tao,Evans D G，et al. Assembly and Structural Characteristics of Organic Anion-pillared Hydrotalcites[J]. Chinese J Process Eng,2002,2(4):355-360(in Chinese).

李殿卿,冯桃,Evans D G,等. 有机阴离子柱撑水滑石的插层组装及超分子结构[J]. 过程工程学报,2002,2(4):355-360.

[12] ZHU Bingyu,ZHANG Zhengqun,LI Gang,et al. Organic Modified Betonite and Its Effect on the Physical Stability of Nicosulfuron Oil Suspension[J]. Chinese J Appl Chem,2009,26(8):881-884(in Chinese).

朱炳煜,张正群,李刚,等. 有机改性膨润土及其对烟嘧磺隆油悬浮体系物理稳定性的影响[J]. 应用化学,2009,26(8):881-884.

[13] Kelessidis V C,Maglione R,Tsamantaki C,et al. Optimal Determination of Rheological Parameters for Herschel Bulkley Drilling Fluids and Impact on Pressure Drop, Velocity Profiles and Penetration Rates During Drilling[J]. J Petrol Sci Eng,2006,53:203-224.

[14] LI Shuping,HOU Wanguo,SUN Dejun,et al. Studies on the Thixotropy of Ferric Aluminum Magnesium Hydroxide/Montmorillonite Suspension[J]. Chem J Chinese Univ,2001,22(7):1173-1176(in Chinese).

李淑萍,侯万国,孙德军,等. Fe-Al-Mg-MMH/钠质蒙脱土分散体系触变性研究[J]. 高等学校化学学报,2001,22(7):1173-1176.

[15] HOU Wanguo,SU Yanlei,SUN Dejun,et al. Study on the Thixotropy of Magnesium Ferric Hydroxide-Montmorillonite Suspension[J]. Acta Chim Sin,2000,58(6):722-726(in Chinese).

侯万国,苏延磊,孙德军,等. Mg-Fe-MMH-钠质蒙脱土分散体系的触变性研究[J]. 化学学报,2000,58(6):722-726.

[16] Wang B,Zhang H,David G,et al. Surface Modification of Layered Double Hydroxides and Incorporation of Hydrophobic Organic Compounds[J]. Mater Chem Phys，2005,92(1):190-196.

[17] XU Li. Study on Intercalation of Mg/Al Layered Double Hydroxides and Its Application in the Treatment of Dyeing Wastewater[D]. Xi′an:Xi′an University of Science Technol,2008(in Chinese).

徐莉. 镁铝水滑石的插层组装及在印染废水处理中的应用研究[D]. 西安:西安科技大学,2008.

Preparation of Dodecyl Sulfonate-Layered Double Hydroxides and Influence on Nicosulfuron Oil Flowable Concentrate Rheological Property

PDF

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	LIAO Kechao1, LU Fusui2*, LIU Cunping1, XIA Hui1. Preparation and Properties of Butylene Fipronil-loaded Microcapsules [J]. Chinese Journal of Applied Chemistry, 2014, 31(09): 1037-1043.
[2]	HUANG Juanping, LI Sufang*, LI Jiao, KANG Meng, WANG Congcong, LIU Tingting. Synthesis and Properties of Waterborne Epoxy Composite Emulsifier [J]. Chinese Journal of Applied Chemistry, 2014, 31(03): 256-261.
[3]	LIAN Yinghui1, LI Lifang2*, ZHAO Fan2, ZHAO Wenjie2. Rheologic Property and Influencing Factors of Sodium Carboxymethyl Cellulose/Montmorillonite Suspension [J]. Chinese Journal of Applied Chemistry, 2013, 30(10): 1208-1214.
[4]	SHANG Jian, YANG Kaikai, LIU Feng*. Application of Benzyl Starch and Alkyl Polysaccharide Glycoside as Mix-emulsifier in Preparation of Aqueous Cyhalofop-butyl Emulsion [J]. Chinese Journal of Applied Chemistry, 2013, 30(09): 1048-1053.
[5]	LIU Jinyan*, LIAO Yongjuan. Water States in Reverse Micelle Formed from C₁₂-S₂-C₁₂·2Br Quaternary Ammonium Dimetric Surfactant Mixed System in Chloroform [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 846-851.
[6]	YU Tao1*, LUO Shiqiong1, DING Wei1, WANG Huimin1, YUAN Dandan1, QU Guangmiao1, LI Zhong2. Effect of the Structure of Alkyl Aryl Sulfonates on the Microemulsive Phase Behavior [J]. Chinese Journal of Applied Chemistry, 2012, 29(09): 1060-1064.
[7]	SUN Tingting, ZHANG Shuqin*, LU Fusui, CHEN Tiantian. Effect of Styrene-Maleic Anhydride Copolymer on the Dispersibility of 20% Diflubenzuron Suspension Concentrate [J]. Chinese Journal of Applied Chemistry, 2012, 29(09): 1046-1052.
[8]	SONG Changping, LIU Junkang, NI Zhongbin, CHEN Mingqing, LIU Shirong*. Preparation of Self-Assembly Polystyrene Sphere Colloid Crystal by a Solvent Evaporation Method [J]. Chinese Journal of Applied Chemistry, 2012, 29(06): 639-642.
[9]	YE Zhiwen . Micelle Aggregation Numbers and Rheological Characterization of C₁₂-3-C₁₂·2Br and C₁₂-3（OH）-C₁₂·2 Br in Aqueous Solution [J]. Chinese Journal of Applied Chemistry, 2012, 29(05): 571-575.
[10]	LI Li1,3, TANG Yongzheng1, JIANG Yuanyuan2, LU Tianhong2, YANG Xujie1, YANG Xiaodi1,2*. Adsorption Behavior of Nicotinamide Adenine Dinucleotide on Nano-α-Aluminum Oxide [J]. Chinese Journal of Applied Chemistry, 2012, 29(05): 551-556.
[11]	ZHU Fusong, YANG Xiuquan*, BAI Liang, FAN Wenjun, ZHANG Jun. Synergetic Effect between Alkylethoxyglucoside and Bentonite Nanoparticles for Stabiling Emulsion [J]. Chinese Journal of Applied Chemistry, 2012, 29(04): 434-439.
[12]	LI Hui, LU Fusui*, WANG Huying, ZHAI Lili, LI Xiuli. Physical Stability of Ametryne Suspension Concentrate [J]. Chinese Journal of Applied Chemistry, 2012, 29(03): 327-331.
[13]	ZHANG Yuan, SHANG Jian, ZHANG Xiaobing, LIU Feng*. Stability Mechanism of Lambda-Cyhalothrin O/W Emulsion Preparated with Esterified Starch as Emulsifier [J]. Chinese Journal of Applied Chemistry, 2012, 29(03): 332-339.
[14]	ZHANG Yuan, LIANG Qifu, ZHANG Xiaobing, LIU Feng*. Preparation of Lambda-Cyhalothrin Oil-in-water Emulsion with Esterified Starch and Methyl Oleate as Emulsifier and Solvent [J]. Chinese Journal of Applied Chemistry, 2012, 29(01): 113-117.
[15]	ZHENG Ou1,2*, WAN Nanhong1, ZHOU Mingming2, ZHOU Longrui2, CHEN Tixian2, LIU Xiaowei2. Effect of pH on the Dispersion Characteristics of Fumed Silica [J]. Chinese Journal of Applied Chemistry, 2011, 28(12): 1448-1452.