Chinese Journal of Applied Chemistry

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Microwave Michael Additions Between Nitrofluorene and Acrylic Esters

HU Weibing1*,HUANG Meng1,FENG Fu1,2, CUI Zhicai1, LIU Xinping1   

  1. (1.School of Chemistry and Environmental Engineering,Hubei Institute for Nationalities,Enshi 445000,China;
    2.Department of Chemistry,Huazhong Normal University,Wuhan 430079,China)
  • Received:2012-08-27 Revised:2012-11-26 Published:2013-06-10 Online:2013-06-10

Abstract: Using nitrofluorene and acrylic esters as precursors, a series of Michael addition products with high yields of 79%~87% was obtained under microwave irradiation(500 W) for 4~5 min in the presence of sodium hydroxide. The strcutures of products were characterized by IR, 1H NMR, MS and elemental analysis. The crystal structure of compound 3b was determined by single X-ray diffraction analysis.

Key words: nitrofluorene, Michael, microwave-assisted

CLC Number: