On the Phase Equilibrium in Coordination of Sm(ClO4)3 with N,N-Bis(antipyrine-4-yl)-1,6-hexanedicarboxamide(BAPHDCA)

Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (3): 82-84.

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On the Phase Equilibrium in Coordination of Sm(ClO₄)₃ with N,N-Bis(antipyrine-4-yl)-1,6-hexanedicarboxamide(BAPHDCA)

Cui Bin, Tang Zongxun, Zhang Fengxing, Guo Zhizhen

Department of Chemistry, Northwest University, Xi'an 710069

Received:1997-08-06 Revised:1998-01-05 Published:1998-06-10 Online:1998-06-10

Abstract

Abstract: In the study of the solubility properties of the system of Sm(ClO₄)₃ BAPHDCA H₂O at 30 ℃ in the whole concentration range by phase equilibrium method a ternary compound Sm(BAPHDCA)₂(ClO₄)₃·H₂O has been found. According to the phase equilibrium results the complex was prepared and characterized by chemical and elemenal analysis, IR spectrometry and TG DTG techniques.

Key words: bis(antipyrine-yl)-hexanedicarboxamide, samarium perchlorate, complex, phase equilibrium

Cui Bin, Tang Zongxun, Zhang Fengxing, Guo Zhizhen. On the Phase Equilibrium in Coordination of Sm(ClO₄)₃ with N,N-Bis(antipyrine-4-yl)-1,6-hexanedicarboxamide(BAPHDCA)[J]. Chinese Journal of Applied Chemistry, 1998, 0(3): 82-84.

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On the Phase Equilibrium in Coordination of Sm(ClO₄)₃ with N,N-Bis(antipyrine-4-yl)-1,6-hexanedicarboxamide(BAPHDCA)

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