Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex

Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (2): 20-23.

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Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex

Shi Tongshun, Liu Wei, Xu Chunfang, Wang Xingqiao, Liu Guofa

Department of Chemistry, Jilin University, Changchun 130023

Received:1997-05-22 Revised:1997-09-28 Published:1998-04-10 Online:1998-04-10

Abstract

Abstract: The title complex TNTBPCo(Ⅱ) was synthesized and characterized by elemental analysis, UV-vis, spectrum, IR photoacoustic spectrum, H NMR and molar conductance measurements. Its electrochemical behavior has been investigated by cyclic voltammetry in DMSO. The half wave potential of [TNTBPCo(Ⅲ)]⁺/TNTBPCo(Ⅱ) was -0.255 V and that of TNTBPCo(Ⅱ)/[TNTBPCo(Ⅰ)]^-1 was -1.175 V. The half wave potential of redox of porphyrin ring [TNTBPCo(Ⅰ)]^-1/[TNTBPCo(Ⅰ)]^-2 was -1.850 V.

Key words: tetranaphthyl tetrabenzoporphyrin, colbalt complex, synthesis, characterization, electrochemical behavior

Shi Tongshun, Liu Wei, Xu Chunfang, Wang Xingqiao, Liu Guofa. Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex[J]. Chinese Journal of Applied Chemistry, 1998, 0(2): 20-23.

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Synthesis and Electrochemical Behavior of Tetra-(1-naphthyl)tetrabenzoporphyrin Cobalt(Ⅱ) Complex

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