Chinese Journal of Applied Chemistry ›› 1998, Vol. 0 ›› Issue (1): 68-70.

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Evaluation of Charge Transport in Polyaniline by Square Wave Voltammetry

Yang Chunhe, Dong Shaojun   

  1. Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1997-04-08 Revised:1997-10-09 Published:1998-02-10 Online:1998-02-10

Abstract: The charge transport rate in polyaniline, which was obtained through electropoly-merization by cyclic voltammetry, was evaluated by the square wave voltammetry and thetime of scale of voltammetry was defined by AC impedance technique.The results show thatthe charge transport in polyaniline is controlled by diffusion.The Dapp and k0 of the redox re-action are determined by COOL algorithm by means of the fast scanning and sampling of thesquare wave voltammetry.

Key words: polyaniline, charge transport, square wave voltammetry, chemically modified electrode