The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (3): 81-83.

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The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature

Zhang Weihua¹, Xin Xinquan²

1. Department of Chemistry, Hubei Normal University, Huangshi 435002;
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093

Received:1996-08-04 Revised:1997-03-11 Published:1997-06-10 Online:1997-06-10

Abstract

Abstract: The solid solid state reaction of 2,2'-(p-phenylenedimethylenethio)diacetic acid with cobalt acetate tetrahydrate has been studied. XRD, IR, ESR, TG-TA and elemental analysis were used to characterize the solid product. The kinetics of the isothermal solid state reaction was investigated by using the electrical conductivity measurement. The kinetics of this system conforms to a A³ mechanism, the activation energy is calculated to be Ea=104.7 kJ/mol.

Key words: p-phenylenedimethylenethio diacetic acid, cobalt acetate tetrahydrate, solid state reaction, kinetics

Zhang Weihua, Xin Xinquan. The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature[J]. Chinese Journal of Applied Chemistry, 1997, 0(3): 81-83.

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The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature

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