[(t-BuCp)2YCH3]2 and Catalytic Activity in Methyl Methacrylate Polymerization

Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (1): 86-88.

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[(t-BuCp)₂YCH₃]₂ and Catalytic Activity in Methyl Methacrylate Polymerization

Hu Jingyu¹, Ren Jingsong¹, Shen Qi²

1. Laboratory of Rare Earth Chemistry and Physics, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022;
2. Department of Chemistry, Suzhou University, Suzhou

Received:1996-04-18 Revised:1996-07-01 Published:1997-02-10 Online:1997-02-10

Abstract

Abstract: The title complex was prepared by the reaction of(t-BuCp)₂YCl in THFwith ether solution of CH₃Li at -78℃. The complex was characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. The complex [(t-BuCp)₂YCH₃]₂ was used as a catalyst for polymerization of MMA and the influence of polymerization conditions on its catalytic activity was investigated.

Key words: yttrium complex, synthesis, catalytic activity, methyl methacrylate

Hu Jingyu, Ren Jingsong, Shen Qi. [(t-BuCp)₂YCH₃]₂ and Catalytic Activity in Methyl Methacrylate Polymerization[J]. Chinese Journal of Applied Chemistry, 1997, 0(1): 86-88.

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[(t-BuCp)₂YCH₃]₂ and Catalytic Activity in Methyl Methacrylate Polymerization

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