Chinese Journal of Applied Chemistry ›› 1997, Vol. 0 ›› Issue (1): 11-15.

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Properties of Perovskite-Type La1-xCuxMnO3 Catalysts

Liang Zhencheng, Qin Yongning, Liao Qiaoli, Qiao Guandong, Qi Xiaozhou   

  1. Department of Chemical Engineering, Tianjin University, Tianjin 300072
  • Received:1996-03-18 Revised:1996-08-26 Published:1997-02-10 Online:1997-02-10

Abstract: The catalytic properties of La1-xCuxMnO3 perovskite type catalysts prepared by coprecipitation have been studied by means of XRD, TPR, TEM, SEM, EMPA, activity evaluation and etc. The results reveal that the activation energy of La1-xCuxMnO3 catalysts decreases with the increase of x from 0 to 0.6 and the activity of the catalysts for COand CH4 oxidation has a maximum point(for COoxidation x =0.4 and for CH4 oxidation x =0.2). It is considered that the above behaviour is caused by the increase of lattice defects and chemical potential of lattice oxygen in catalysts with the increase of x.

Key words: perovskite-type catalyst, property, copper substitution, catalytic oxidation, catalytic activity