Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1,4,2-Diazaphospholidin-5-one-2-Oxides

Chinese Journal of Applied Chemistry ›› 1996, Vol. 0 ›› Issue (5): 29-32.

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Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1,4,2-Diazaphospholidin-5-one-2-Oxides

Chen Ruyu, He Liangnian, Yang Xiufeng

Institute of Elemento-Organic Chemistry, Nankai University, The National Key Laboratory of Elemento-Organic Chemistry, Tianjin 300071

Received:1995-12-28 Revised:1996-05-17 Published:1996-10-10 Online:1996-10-10

Abstract

Abstract: A series of 1-(p-toluenesulfonyl)-2-phenoxy-3-aryl-4-phenyl-1,4,2-diazaphospholidin-5-one-2-oxides (2) has been synthesized by the. Mannich-type reaction of 1-phenyl-3- (ptoluenesulfonyl) urea(1), substituted benzaldehydes and triphenyl phosphite in anhydrous toluene. The side reactions were discussed. The structures of new compounds were characterized by ¹H NMR, ³¹P NMR, elemental analysis, MS and IR spectra. The results of preliminary bioassay showed that the compound 2 possesses good selective herbicidal activity against rape.

Key words: diazaphospholidin-one, synthesis, herbicidal activity

Chen Ruyu, He Liangnian, Yang Xiufeng. Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1,4,2-Diazaphospholidin-5-one-2-Oxides[J]. Chinese Journal of Applied Chemistry, 1996, 0(5): 29-32.

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Synthesis and Herbicidal Activity of 1-(p-Toluenesulfonyl)-2-Phenoxy-3-Aryl-4-Phenyl-1,4,2-Diazaphospholidin-5-one-2-Oxides

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