SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH3)4CO3)Cl and (Co(en)2CO3)Cl WITH NH4SCN

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (2): 33-37.

• Full Papers • Previous Articles Next Articles

SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN

Zhuang Jia, Cheng Quan, Xin Xinquan, Zheng Limin

Department of Chemistry, Nanjing University, Nanjing 210008

Received:1991-04-08 Revised:1991-06-26 Published:1992-04-10 Online:1992-04-10

Abstract

Abstract: Solid state substitution reactions take place between (Co(NH₃)₄CO₃)Cl or (Co(en)₂CO₃) Cl with NH₄SCN at 100℃, with the non-volatized CO₃^2- being substituted outside the inner coordination sphcrc by SCN^-. Trans^-(Co(NH₃)₄(NCS)₂)Cl is formed in the reaction of (Co(NH₃)₄CO₃)Cl with NH₄SCN. However, in the reaction bctwccn(Co(en)₂CO₃)Cl and NH_SCN, Cis-Co(en)₂(NCS)₂Cl is at first formed transforming into trans-isomer ultimately. Two reactions are believed to proceed through S_N2 mechanism.

Key words: solid state reaction, substitution, (Co(NH₃)₄CO₃)Cl, (Co(en)₂CO₃)Cl

Zhuang Jia, Cheng Quan, Xin Xinquan, Zheng Limin. SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN[J]. Chinese Journal of Applied Chemistry, 1992, 0(2): 33-37.

[1]	YUAN Ning,DU Bingjie,JIA Xiaoxia,YANG Jiangfeng,LI Jinping. Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials [J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 500-510.
[2]	XU Zeqing, GAO Baojiao*, HOU Xiaodong. Synthesis of Benzoic Acid Derivative-Bonded Polystyrene Ligand and Photoluminescence Properties of Its Complex with Eu(Ⅲ) Ion [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 133-139.
[3]	HE Jinmei*, QU Mengnan, HE Zhongsen. One Pot Continuous Reaction of Benzoin Condensation and Allylic Nucleophilic Substitution Using N-Heterocyclic Carbenes and Nickel(Ⅱ) Chloride as Catalysts [J]. Chinese Journal of Applied Chemistry, 2013, 30(07): 852-854.
[4]	WANG Mingjuan, GAO Baojiao*, DU Junmei. Preparation of Naphthoic acid -functionalized Polysulfoneand Preliminary Exploration of Fluorescence Emissionof Formed Polymer-Rare Earth Eu(Ⅲ) Complexes [J]. Chinese Journal of Applied Chemistry, 2013, 30(03): 283-289.
[5]	LI Yan1, HOU Wan-Guo2*. Adsorption of Low-substituted Cationic Starch on Aluminum Magnesium Hydrotalcite Analogue [J]. Chinese Journal of Applied Chemistry, 2010, 27(07): 811-816.
[6]	LIU Lan, NIE Fu-De*, ZENG Gui-Yu, QIAO Zhi-Qiang. Preparation of NiO Nanorods by a Solid State Reaction at Low Temperatures under an Ultrasonic Airflow [J]. Chinese Journal of Applied Chemistry, 2010, 27(04): 454-457.
[7]	Zhong Hui, Guo Linghong. Synthetic Kinetics of Solid State Reaction of H₂TiO₂ Type Ion exchangers [J]. Chinese Journal of Applied Chemistry, 1998, 0(3): 103-105.
[8]	Hu Yuan, Shao Zonglong, Dong Hua, Yu Yaping, Mao Yuhua, Fan Weicheng. Synthesis of 2, 2, 4, 4-Tetra(4′-hydroxymethylphenoxy)-6, 6-diphenylcyclotriphosphazene [J]. Chinese Journal of Applied Chemistry, 1998, 0(1): 22-24.
[9]	Zhang Weihua, Xin Xinquan. The Solid Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)Diacetic Acid with Cobalt Acetate Tetrahydrate at Low Heating Temperature [J]. Chinese Journal of Applied Chemistry, 1997, 0(3): 81-83.
[10]	Liang Zhencheng, Qin Yongning, Liao Qiaoli, Qiao Guandong, Qi Xiaozhou. Properties of Perovskite-Type La_1-xCu_xMnO₃ Catalysts [J]. Chinese Journal of Applied Chemistry, 1997, 0(1): 11-15.
[11]	Long Deliang, Liang Bin, Xin Xinquan. Solid State Reaction at Low-heating and Room Temperatures:Application in Synthetic Chemistry [J]. Chinese Journal of Applied Chemistry, 1996, 0(6): 1-6.
[12]	Yang Jianmei, Su Qiang. Effect of Substitution of Chromium Ion on the Properties of LaGa_1-xCr_xO₃ [J]. Chinese Journal of Applied Chemistry, 1996, 0(6): 46-48.
[13]	Pan Yan, Huang Yuhui, Cong Guangmin. Modification of Poly(2,6-dimethyl-1,4-phenylene Oxide) with Nitro or Amino Functional Groups [J]. Chinese Journal of Applied Chemistry, 1996, 0(5): 10-13.
[14]	Gong Jian, Wei Yonghui, Qu Lunyu. Stability of Peroxyniobium-Containing Tungstophosphoric Heteropoly Complexes [J]. Chinese Journal of Applied Chemistry, 1996, 0(5): 70-72.
[15]	Fu Xiangkai, Wen Shuying, Kang Wei. Quaternary Compounds of Zirconium Dibutylamino-methylphosphonate and Thier PTC Activities [J]. Chinese Journal of Applied Chemistry, 1995, 0(2): 20-23.

SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅩⅩⅢ. THE SOLID STATE SUBSTITUTION REACTION OF (Co(NH₃)₄CO₃)Cl and (Co(en)₂CO₃)Cl WITH NH₄SCN

PDF

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments