SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF POLY(METHYL METHACRYLATE-co-BUTYL ACRYLATE) WITH UNIFORM POLYOXYETHYLENE SIDE CHAINS

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (1): 1-6.

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SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF POLY(METHYL METHACRYLATE-co-BUTYL ACRYLATE) WITH UNIFORM POLYOXYETHYLENE SIDE CHAINS

Guo Junshe¹, Xie Hongquan¹, Liu Xinhua²

Department of Chemistry, Huazhong University of Science and Technology, Wuhan430074

Received:1990-12-30 Revised:1991-03-28 Published:1992-02-10 Online:1992-02-10

Abstract

Abstract: In the terpolymerization of polyoxyethylene macromer, methyl methacrylate and butyl acrylate the polymerization rate and the effects of various factors on grafting efficiency and molecular weight of the terpolymers were studied. The terpolymers were purified by extractions and characterized by IR, NMR, DSC and membrane osmometry. The average grafting number was determined to be about 10. The terpolymers possess good emulsifying property, phase transfer catalytic ability and behave like a thermoplastic elastomer.

Key words: macromer, emulsifier, graft polymer, amphiphilic copolymer, thermoplastic elastomer, phase transfer catalyst

Guo Junshe, Xie Hongquan, Liu Xinhua. SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF POLY(METHYL METHACRYLATE-co-BUTYL ACRYLATE) WITH UNIFORM POLYOXYETHYLENE SIDE CHAINS[J]. Chinese Journal of Applied Chemistry, 1992, 0(1): 1-6.

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SYNTHESIS, CHARACTERIZATION AND PROPERTIES OF POLY(METHYL METHACRYLATE-co-BUTYL ACRYLATE) WITH UNIFORM POLYOXYETHYLENE SIDE CHAINS

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