Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (5): 68-71.

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CONDUCTIVITY OF CHARGE TRANSFER COMPLEX OF PYRIDAZINE WITH IODINE

Bi Xiantong, Zhu Daoben, Ye Cheng, Li Suzhen, Wan Meixiang, Yao Youxin, Qian Renyuan   

  1. Institute of Chemistry Academia Sinica, Beijing 100080
  • Received:1989-10-23 Revised:1990-03-17 Published:1990-10-10 Online:1990-10-10

Abstract: The pyridazine-I2 charge transfer complexes have been found to have an electrical conductivity of 1-102 S/cm and a mixture of the complex with solid I2 up to 98% showed a conductivity greater than 1 S/cm. The voltage shorted compaction technique was used for the conductivity measurement. The complex sample showed a 20% increase in conductivity fromroom temperature to-30℃ and the value then decreases with further lowering the temperature to-10% of σRT at-100℃. XPS and laser Raman spectral data are also reported.

Key words: pyridazine, charge transfer complex, conductivity