SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K3(Co(CN)5L)

Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (2): 65-68.

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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)

Yuan Jinhua, Xin Feibo, Xin Xinquan, Dai Anbang

Coordination Chemistry Institute, Nanjing University, Nanjing 210008

Received:1988-11-30 Revised:1989-08-23 Published:1990-04-10 Online:1990-04-10

Abstract

Abstract: Thermal decomposition of the title compounds(L=NO^-, CN^-, NO₂^-, N₃^-)in heliumand vacuum has been studied by gas chromatography and quadrupole mass spectrometry. Theresult shows that the substitute ligand released prior to cyano group and the order of thedecomposition temperature of substituted ligands is NO^- < N₃^- < NO₂^- < CN^-. Appearance of potassiun cyanocobaltate(Ⅲ)in decomposition products shows a rearlan-gement occured among solid. compounds during the decomposition reaction.

Key words: solid reaction, coordination chemistry, cobaltic pentacyanide complex, thermal decomposition

Yuan Jinhua, Xin Feibo, Xin Xinquan, Dai Anbang. SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)[J]. Chinese Journal of Applied Chemistry, 1990, 0(2): 65-68.

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SOLID STATE REACTIONS OF COORDINATION COMPOUNDS ⅩⅩⅪ THERMAL DECOMPOSITION OF K₃(Co(CN)₅L)

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