Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (1): 62-65.

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STRUCTURAL STUDY OF CROSSLINKED COPOLYMERS(ERPEO)AND THEIR COMPLEXES WITH SODIUM THIOCYANATE

Zhang Hongfang, Mo Zhishen, Peng Xingsheng, Wang Fosong   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1989-02-25 Revised:1989-07-15 Published:1990-02-10 Online:1990-02-10

Abstract: The structure of the crosslinked copolymers(and/or blends)of epoxy resin/polyethyleneoxide(ER/PEO)and their complexes with sodium thiocyanate after extraction has beenstudied by using WAXD, SAXS, DSC and SEM methods. The r?sults showed that thesamples after extraction have an amorbhous structures of the crosslinked copolymers(ER-PEO). The crystallinity of the complexes ER/PEO-NaSCN was decreased as compared withcorresponding blends ER/PEO, due to the presence of Na ion.

Key words: polymer solid electrolyte, epoxy resin, poly(ethylene oxide), crosslinked copolymer, complex