THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE

Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (1): 52-56.

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THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE

Wu Jianhua¹, Wang Boyi¹, Zheng Peiju¹, Xie Gaoyang², Zhang Zhen²

1. Center of Analysis and Measurement, Fudan University, Shanghai;
2. Chemistry Department, Fudan University, Shanghai

Received:1985-12-24 Published:1988-02-10 Online:1988-02-10

Abstract

Abstract: The crystal structure of [Nd(DMSO)₅(H₂O)₃]Cl₃·H₂O was determined on an ENRAFNONIUS CAD₄ diffractometer with X-ray intensity data collected in 0°<2θ<50°. The space group is P₁ with a=9.800(1), b=10.153(1), c=14.757(2)Å; α=93.07(1), β=100.21(1),γ=99.71(1)°, Z=2. The structure was solved by Patterson method and refined with a fullmatrix least-squares procedure to R=0.036. Nd(Ⅲ) ions are coordinated by eight oxygen atoms forming a distorted dodecahedron. The crystal is stabilized through ionic bonds and hydrogen bonds as well.

Key words: Crystall structure, Complex, Neodymium chloride, X-ray diffraction, Dimethyl sulfoxide

Wu Jianhua, Wang Boyi, Zheng Peiju, Xie Gaoyang, Zhang Zhen. THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE[J]. Chinese Journal of Applied Chemistry, 1988, 0(1): 52-56.

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THE CRYSTAL STRUCTURE OF NEODYMIUM CHLORIDE WITH DIMETHYL SULFOXIDE

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