Synthesis and Characterization of Two β-Diketones with Carbazole Group

doi:10.3724/SP.J.1095.2011.00675

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (11): 1239-1243.DOI: 10.3724/SP.J.1095.2011.00675

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Synthesis and Characterization of Two β-Diketones with Carbazole Group

TANG Huaijun^1,2*, ZHANG Meifang², ZHANG Zhiguo², SHI Qing², ZHANG Keli^2*

(1.Institute of Polymer Optoelectronic Materials and Devices,Key Lab of Specially Functional
Materials of the Ministry of Education,South China University of Technology,Guangzhou 510640;
2.College of Chemistry and Molecular Sciences,Wuhan University,Wuhan 430072)

Received:2010-11-15 Revised:2011-01-11 Published:2011-11-10 Online:2011-11-10
Contact: Keli Zhang

Abstract

Abstract:

Two β-diketones with carbazole group were synthesized from carbazole and biphenyl. The β-diketones were characterized by 1H NMR, 13C NMR, MS, elemental analyses, thermoanalysis, UV-Vis absorption spectra and photoluminescence(PL) spectra. The β-diketones have high thermal stability, their 5% mass-reduction temperatures(ΔT5%) are 319 ℃ and 356 ℃, respectively. Their PL spectra lie in blue light zone with the maximum emission peaks of 443 nm and 455 nm. They are potential ligands for synthesizing metal ion complexes targeted for light-emitting materials.

Key words: β-diketones, carbazole, biphenyl, Claisen condensation

CLC Number:

O621.3

TANG Huaijun1,2*, ZHANG Meifang2, ZHANG Zhiguo2, SHI Qing2, ZHANG Keli2*. Synthesis and Characterization of Two β-Diketones with Carbazole Group[J]. Chinese Journal of Applied Chemistry, 2011, 28(11): 1239-1243.

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Synthesis and Characterization of Two β-Diketones with Carbazole Group

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