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应用化学
Chinese Journal of Applied Chemistry    2009, Vol. 26 Issue (10) : 1144-1148     DOI:
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Synthesis and Characterization of Molecularly Imprinted Polymer Microspheres for Recognition of Chlorpyrifos
 HUAI Lu-Feng, YANG Ming, LIU Jun, HU Juan
(School of Chemical and Environmental Engineering,Wuhan Polytechnic University,Wuhan 430023)
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Abstract  

Molecularly imprinted polymeric microspheres (MIPMs) had been prepared by a one-step swelling polymerization method in aqueous system using micron-polystyrene microspheres which was gained by emulsifer-free polymerization as seeds and using Chlorpyrifos as template molecules. The selective binding characteristics of MIPMs were evaluated by ultraviolet spectrometry. The infrared spectrometry(IR) of the polymer further indicated that there were some functional groups in the moleculary imprinted polymer which could interact on the template. Subsequent morphological characterizations of the MIPMs by scanning electron microscope (SEM), show that they diameters were between 0.5~3μm(as opposed to 2~3μm for the UMIPMs), surface rugosity and high porosities with pore, it was facility related to the template and binding sites , so to obtain a high load, affinity and selectivity to template molecules. Scatchard analysis suggested the MIPMs recognizing Chlorpyrifos with two classes of binding sites. The calculated dissociation constant KD1 and apparent maximumnumber Bmax1 of binding siteswith high affinity were 0.526 mmol/L and 35.91 μmol/g respectively, while KD2 and Bmax2 of binding siteswith low affinity were 2.19 mmol/L and 83.87 μmol/g.

Keywords Molecularly imprinted polymeric microspheres      Single-step swelling polymerization      Chlorpyrifos      Binding sites     
CLC:  O631  
Received: 2008-09-27      Revised: 2009-01-21     
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HUAI Lu-Feng
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HU Juan
Cite this article:   
HUAI Lu-Feng,YANG Ming,LIU Jun, et al. Synthesis and Characterization of Molecularly Imprinted Polymer Microspheres for Recognition of Chlorpyrifos[J]. Chinese Journal of Applied Chemistry, 2009, 26(10): 1144-1148.
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http://yyhx.ciac.jl.cn/EN/     OR     http://yyhx.ciac.jl.cn/EN/Y2009/V26/I10/1144
[1] LI Li-Fang1*, KONG Xiang-Jie2, DAI Shao-Kai1, WANG Li2. Effect of electrolytes and pH on the transparent temperature region of Chlorpyrifos microemulsion systems[J]. Chinese Journal of Applied Chemistry, 2010, 27(05): 558-562.
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