Preparation and Application of Attapulgite Based Nano⁃controlled Chlorpyrifos

doi:10.19894/j.issn.1000-0518.220109

Chinese Journal of Applied Chemistry ›› 2022, Vol. 39 ›› Issue (11): 1774-1782.DOI: 10.19894/j.issn.1000-0518.220109

• Full Papers • Previous Articles

Preparation and Application of Attapulgite Based Nano⁃controlled Chlorpyrifos

Dong-Qing CAI¹, Jing ZHANG¹, Qing-Chuan WU², Jing-Hong YE¹, Lin-Ying WANG¹, Dong-Fang WANG¹()

^1.School of Environmental Science and Engineering，Donghua University，Shanghai 201620，China
^2.Hefei Institute of Physical Science，Chinese Academy of Sciences，Hefei 230001，China

Received:2022-04-04 Accepted:2022-07-19 Published:2022-11-01 Online:2022-11-09
Contact: Dong-Fang WANG
About author:dfwang@dhu.edu.cn
Supported by:
the Science and Technology Service Program of Chinese Academy of Science(KFJ?STS?QYZD?199);the Fundamental Research Funds for the Central Universities(2232020D?22);the National Natural Science Foundation of China(52000025);the Key R&D Program of Guangdong Province(2020B0202010005);the Key R&D Program of Inner Mongolia Autonomous Region(2021GG0300)

1. Preparation and Application of Attapulgite Based Nano-controlled Chlorpyrifos.pdf(242KB)

Abstract

Abstract:

In order to improve the utilization ratio of pesticides and reduce the harm of pesticides to the environment， nano loss control chlorpyrifos （NLCC） is fabricated by loading chlorpyrifos （CPF） on attapulgite （ATP）. The loss control effect of ATP on CPF is studied by filter paper and sugarcane leaves and the interaction of NLCC system is studied by SEM， FT-IR， XRD， and so on. Furthermore， the loss control effect of ATP on CPF is also investigated by field test. These results show that ATP could adsorb CPF by hydrogen bonds and the adhesion amount of CPF before and after rainfall increases by 5.4 μg and 5.6 μg， respectively. The maximum loading amount of attapulgite to chlorpyrifos is 500 mg/g. In addition， the mortality of corn borers increases by 20% respectively. Moreover， the field test also shows that NLCC could reduce 21% of sugarcane damaged by pests， 4.3% of sugarcane stalks damaged by pests， and the wormholes of 2 per plant and increase the height by 23.1 cm. These results indicate that NLCC could effectively reduce pests and promote the growth of sugarcane. Therefore， this study provides a simple and practical method for reducing pesticide loss， improving pesticide utilization rate， and decreasing environmental pollution， which has a high application value for the development of green agriculture.

Key words: Attapulgite, Chlorpyrifos, Loss control, Hydrogen bonds, Field test

CLC Number:

O629

Dong-Qing CAI, Jing ZHANG, Qing-Chuan WU, Jing-Hong YE, Lin-Ying WANG, Dong-Fang WANG. Preparation and Application of Attapulgite Based Nano⁃controlled Chlorpyrifos[J]. Chinese Journal of Applied Chemistry, 2022, 39(11): 1774-1782.

Figures/Tables 7

Fig.1 Schematic illustration of the fabrication process and the mechanism of NLCC

Fig.2 SEM images of filter paper （A）， ATP+filter paper （B）， NLCC+filter paper （C）. Influence of ATP amount on the adhesion amount of CPF in the surface of filter paper （D）

Fig.3 SEM images of sugarcane leaf （A）， CPF （B）， CPF+sugarcane leaf （C）， ATP+sugarcane leaf （D） and NLCC+sugarcane leaf （E）； Influence of ATP amount on the adhesion amount of CPF in the surface of sugarcane leaf （F）

Fig.4 FT-IR spectra （A） and XRD patterns （B） of ATP， CPF and ATP+CPF； N2 adsorption-desorption isotherms （C） and pore size distributions （D） of ATP and ATP+CPF； TGA curves of ATP （E） and ATP+CPF （F）； Schematic diagram of CPFFP adsorption by ATP （G）

Fig.5 （A） Digital photographs of corn borers treated by CPF， NLCC and control check （ck） before and after simulated precipitation. （B） The mortality of corn borers within 6 h

Fig.6 Loading amount of CPF in different concentration by 50 mg ATP

Fig.7 （A） Percentage of sugarcane damaged by pests；（B） Percentage of sugarcane stalks damaged by pests；（C） The number of wormholes on sugarcane；（D） Sugarcane height： ck and NLCC

References 25

1	SINGH A， DHIMAN N， KAR A K， et al. Advances in controlled release pesticide formulations： prospects to safer integrated pest management and sustainable agriculture［J］. J Hazard Mater， 2020， 385： 121525.
2	ZHAO X， CUI H X， WANG Y， et al. Development strategies and prospects of nano-based smart pesticide formulation［J］. J Agric Food Chem， 2018， 66（26）： 6504-6512.
3	BEKETOV M A， KEFFORD B J， SCHAFER R B， et al. Pesticides reduce regional biodiversity of stream invertebrates［J］. Proc Natl Acad Sci USA， 2013， 110（27）： 11039-11043.
4	SHOU C G， DU H S， LIU X P. Research progress of source and mechanism of agricultural non-point source pollution in China［J］. Appl Ecol Environ Res， 2019， 17（5）： 10611-10621.
5	SILVA V， MOL H G J， ZOMER P， et al. Pesticide residues in European agricultural soils-a hidden reality unfolded［J］. Sci Total Environ， 2019， 653： 1532-1545.
6	KIM K H， KABIR E， JAHAN S A. Exposure to pesticides and the associated human health effects［J］. Sci Total Environ， 2017， 575： 525-535.
7	陈超文，刘彬，吴正岩. 基于水凝胶体系的磷酸根响应控释农药释放行为分析［J］. 分析化学， 2020， 48（11）： 1583-1589.
	CHEN C W， LIU B， WU Z Y. Release behavior of hydrogel-based PO₄ ^3--responsive controlled release pesticide［J］. Chinese J Anal Chem， 2020， 48（11）： 1583-1589.
8	BHAGAT D， SAMANTA S K， BHATTACHARYA S. Efficient management of fruit pests by pheromone nanogels［J］. Sci Rep， 2013， 3： 1294.
9	KUMAR S， CHAUHAN N， GOPAL M， et al. Development and evaluation of alginate-chitosan nanocapsules for controlled release of acetamiprid［J］. Int J Biol Macromol， 2015， 81： 631-637.
10	LI R X， XIE H G， ZHANG C G， et al. ROS-responsive polymeric micelle for improving pesticides efficiency and intelligent release［J］. J Agric Food Chem， 2020， 68（34）： 9052-9060.
11	NATARAJAN J V， NUGRAHA C， NG X W， et al. Sustained-release from nanocarriers： a review［J］. J Controlled Release， 2014， 193： 122-138.
12	王文波，牟斌，张俊平，等. 凹凸棒石：从矿物材料到功能材料［J］. 中国科学：化学， 2018， 48（12）： 1432-1451.
	WANG W B， MU B， ZHANG J P， et al. Attapulgite： from clay minerals to functional materials［J］. Sci Sin： Chim， 2018， 48（12）： 1432-1451.
13	周红军，周新华，黄俊源，等. 啶虫脒/席夫碱改性凹凸棒土缓释体系的制备与性能［J］. 精细化工， 2017， 34（3）： 256-261， 293.
	ZHOU H J， ZHOU X H， HUANG J Y， et al. Preparation and properties of slow-released system of acetamiprid/schiff base modified attapulgite［J］. Fine Chem， 2017， 34（3）： 256-261， 293.
14	CHENG W C， DING C C， SUN Y B， et al. Fabrication of fungus/attapulgite composites and their removal of U（VI） from aqueous solution［J］. Chem Eng J， 2015， 269： 1-8.
15	DUAN Z H， ZHAO Q N， WANG S， et al. Novel application of attapulgite on high performance and low-cost humidity sensors［J］. Sens Actuators， B， 2020， 305： 127534.
16	XIE L H， LIU M Z， NI B L， et al. Slow-release nitrogen and boron fertilizer from a functional superabsorbent formulation based on wheat straw and attapulgite［J］. Chem Eng J， 2011， 167（1）： 342-348.
17	SUN X， LIU Z J， ZHANG G L， et al. Reducing the pollution risk of pesticide using nano networks induced by irradiation and hydrothermal treatment［J］. J Environ Sci Health， Part B， 2015， 50（12）： 901-907.
18	CAI D Q， WANG L H， ZHANG G L， et al. Controlling pesticide loss by natural porous micro/nano composites： straw ash-based biochar and biosilica［J］. ACS Appl Mater Interfaces， 2013， 5（18）： 9212-9216.
19	HUAGN Y H， ZHANG W P， PANG S M， et al. Insights into the microbial degradation and catalytic mechanisms of chlorpyrifos［J］. Environ Res， 2021， 194：110660.
20	XIANG Y B， WANG M， SUN X， et al. Controlling pesticide loss through nanonetworks［J］. ACS Sustainable Chem Eng， 2014， 2（4）： 918-924.
21	XIANG Y B， HAN J， ZHANG G L， et al. Efficient synthesis of starch-regulated porous calcium carbonate micropheres as a carrier for slow-release herbicide［J］. ACS Sustainable Chem Eng， 2018， 6（3）： 3649-3658.
22	BHAVYA M B， MANIPPADY S R， SAXENA M， et al. Gold nanorods as an efficient substrate for the detection and degradation of pesticides［J］. Langmuir， 2020， 36（26）： 7332-7344.
23	XIANG Y B， ZHANG G L， CHEN C W， et al. Fabrication of a pH-responsively controlled-release pesticide using an attapulgite-based hydrogel［J］. ACS Sustainable Chem Eng， 2018， 6（1）： 1192-1201.
24	XU J L， REN S B， KANG C H， et al. Study on the ball milling modification of attapulgite［J］. Mater Res Express， 2020， 7（11）： 115006.
25	LIU J X， ZHANG X G， ZHANG Y Q. Preparation and release behavior of chlorpyrifos adsolubilized into lay-ered zinc hydroxide nitrate intercalated with dodecylbenzenesulfonate［J］. ACS Appl Mater Interfaces， 2015， 7（21）： 11180-11188.

[1]	CHENG Yinjie, ZHANG Lu, HU Renjie, WANG Ying, JIN Xuexin, QIU Shuo, ZHANG Haoyan, JIANG Dawei. Preparation and Characterization of Hydrogen-Bonded Carbon Nanotubes Reinforced Self-healing Composites [J]. Chinese Journal of Applied Chemistry, 2020, 37(10): 1147-1155.
[2]	LI Jingping, YANG Shihai, LIU Yang, BO Wenbo. Preparation of Attapulgite Clay Supported Nano TiO₂-Fe₃O₄ Adsorbent and Removal of Cr(Ⅵ) [J]. Chinese Journal of Applied Chemistry, 2019, 36(3): 324-334.
[3]	XU Hui, TANG Jin, LI Chunlei, CHEN Yong. Polyaniline/attapulgite-supported Nanoscale Zero-valent Iron for Removing Methyl Orange in Aqueous Solution [J]. Chinese Journal of Applied Chemistry, 2016, 33(1): 92-97.
[4]	FENG Huixia*, GAO Xiaohong, CHEN Nali, DUAN Lingling, ZHANG Juan, LI Hanfeng. Catalytic Performance of Cobalt-Schiff Base-Chitosan/attapulgite for Epoxidation of Styrene [J]. Chinese Journal of Applied Chemistry, 2014, 31(02): 159-164.
[5]	ZHU Weiju, GAO Hua, LI Cun*, WU Zhenyu, FANG Min. Preparation and Adsorption Activities of Attapulgite Modified by Amino-silane Coupling Agent [J]. Chinese Journal of Applied Chemistry, 2012, 29(02): 180-185.
[6]	ZHANG Qianghua1,2, SHI Yingying2, XIONG Qingping2, ZHONG Qin1*. The Determination of Trace Amount of Pb by Flame Atomic Absorption Spectrometry after Separation and Preconcentration with Molecular Imprinting of Chitosan/Attapulgite [J]. Chinese Journal of Applied Chemistry, 2011, 28(09): 1073-1081.
[7]	WU Jie1*, JIANG Jinlong1, XUE Yinfei2. Preparation and Characterization of Attapulgite Supported AlCl3 Catalyst and Its Catalytic Properties [J]. Chinese Journal of Applied Chemistry, 2011, 28(07): 791-797.
[8]	CHEN Tiantian1, WEI Changmei1*, XUE Ailian1, WANG Jintang2. Adsorption of Methyl Orange on Guanidine Modified Attapulgite [J]. Chinese Journal of Applied Chemistry, 2011, 28(07): 809-814.
[9]	MIN Shi-Xiong*, WANG Fang, WEI Li-Qiang, WANG Yong-Sheng, AN Hong-Gang, WU Dong-Qing. Preparation and Photocatalytic Activity of Fe3+ Doped TiO2/Attapulgite Composite Photocatalyst [J]. Chinese Journal of Applied Chemistry, 2010, 27(06): 700-704.
[10]	LI Li-Fang1*， KONG Xiang-Jie2, DAI Shao-Kai1， WANG Li2. Effect of electrolytes and pH on the transparent temperature region of Chlorpyrifos microemulsion systems [J]. Chinese Journal of Applied Chemistry, 2010, 27(05): 558-562.
[11]	ZHANG Li-Li1,2, LV Fu-Jian1, LIU Jian-Quan1, TANG Chao1, WANG Xin1*. Synthesis of Attapulgite-SnO2-TiO2 Nanocomposites and Their Photocatalytic Property [J]. Chinese Journal of Applied Chemistry, 2010, 27(01): 63-68.
[12]	HUAI Lu-Feng, YANG Ming, LIU Jun, HU Juan. Synthesis and Characterization of Molecularly Imprinted Polymer Microspheres for Recognition of Chlorpyrifos [J]. Chinese Journal of Applied Chemistry, 2009, 26(10): 1144-1148.

Preparation and Application of Attapulgite Based Nano⁃controlled Chlorpyrifos

RichHTML

PDF

Supplement

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 7

References 25

Related Articles 12

Recommended Articles

Metrics

Comments