Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant

doi:10.19894/j.issn.1000-0518.200241

Chinese Journal of Applied Chemistry ›› 2021, Vol. 38 ›› Issue (2): 220-227.DOI: 10.19894/j.issn.1000-0518.200241

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Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant

YANG Wei-Guang, CAO Yu-Peng, JU Hong-Bin, WANG Ya-Kui, GENG Tao, JIANG Ya-Jie^*

China Research Institute of Daily Chemical Industry Co., Ltd, Taiyuan 030001, China

Received:2020-08-12 Accepted:2020-10-15 Published:2021-02-01 Online:2021-04-10
Supported by:
National Key Research and Development Project of China (No.2017YFB0308900) and the Project of JALA Research Funds (No.JALA 2018)

Abstract

Abstract: Oleamide quaternary ammonium Gemini surfactants GS-1, GS-2, GS-3 were synthesized by the reaction of Oleamide propyl dimethylamine and 1,3-dichloro-2-propanol, 1,4-dibromo-2-butene and 1,4-dibromo-butane, respectively. The structures of GS-1, GS-2, and GS-3 were characterized by Fourier-transform infrared (FT-IR) spectrometry and proton nuclear magnetic resonance (¹H NMR), and their Krafft temperature, surface activity, emulsification performance, foam performance, and wettability were measured. The results show that three kinds of Gemini surfactants GS-1, GS-2, GS-3 are successfully prepared, and their Krafft temperatures are all less than 0 ℃, which provides a theoretical possibility for their use in low temperature environments with maintained high surface activity. Then, the critical micelle concentration (CMC) values of GS-1, GS-2, GS-3 are 7.7×10^-5, 7.08×10^-5, and 2.63×10^-6 mol/L, respectively, which are consistent with the expected results. The CMC value of the Gemini surfactant is 1~2 orders of magnitude lower than that of the conventional surfactant single alkyl chain. In addition, the synthesized surfactants all show good surface a ctivity, emulsifying properties, and the ability to stabilize foam.

Key words: Gemini surfactant, Eco-friendly substances, Surface activity

CLC Number:

O647.2

YANG Wei-Guang, CAO Yu-Peng, JU Hong-Bin, WANG Ya-Kui, GENG Tao, JIANG Ya-Jie. Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant[J]. Chinese Journal of Applied Chemistry, 2021, 38(2): 220-227.

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Synthesis and Properties of Oleamide Quaternary Ammonium Gemini Surfactant

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