Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate

doi:10.11944/j.issn.1000-0518.2017.04.160295

Chinese Journal of Applied Chemistry ›› 2017, Vol. 34 ›› Issue (4): 414-422.DOI: 10.11944/j.issn.1000-0518.2017.04.160295

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Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate

CHENG Hongyu^a,HU Xiaoxia^a,ZHAO Lin^a,WANG Fang^b,LI Rong^c,XING Yanjun^a^*()

^aCollege of Chemistry,Chemical Engineering and Biotechnology,Donghua University,Shanghai 201620,China
^bSchool of Chemistry and Chemical Engineering,University of South China,Hengyang,Hu'nan 421001,China
^cNational Engineering Research Center for Dyeing &Finishing of Textiles,Donghua University,Shanghai 201620,China

Received:2016-07-15 Accepted:2016-11-09 Published:2017-03-31 Online:2017-03-31
Contact: XING Yanjun
Supported by:
Supported by the National Science and Technology Ministry(No.2012BAK30B03);Fundamental Research Funds for the Central Universities(No.2232013A3-05, No.CUSF-DH-D-2014036)

Abstract

Abstract:

ZrOCl₂, NiCl₂ and NaH₂PO₄ were used as raw materials to prepare nickel zirconium phosphate(NiZr(PO₄)₂·4H₂O, NiZrPs) by a microwave-assisted method at lower temperature and atmospheric pressure. The influence of three different kinds of surfactants on the phase, particle size and morphology of NiZrPs was studied. The results show that the addition of surfactant can reduce the particle size. Compared with sodium dodecyl sulfate(SDS), polyvinylpyrrolidone K30(PVP-K30) and hexadecyltrimethyl ammonium bromide(CTAB) can restrain the growth of particles more efficiently, resulting in a smaller average particle size. Moreover, the visible-light photocatalytic property of NiZrPs was studied based on methylene blue(MB) as a simulated wastewater. As a result, the visible-light apparent dye decolorization efficiency of NiZrP prepared with PVP-K30 is 49.0% which is much higher than that of the other two products. This work developed a new method for the preparation and application of new type zirconium phosphate complex salt.

Key words: nickel zirconium phosphate, microwave-assisted preparation, surfactant, visible-light photocatalysis, dye degradation

CHENG Hongyu, HU Xiaoxia, ZHAO Lin, WANG Fang, LI Rong, XING Yanjun. Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate[J]. Chinese Journal of Applied Chemistry, 2017, 34(4): 414-422.

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Microwave-assisted Preparation and the Visible-light Photocatalytic Properties of Nickel Zirconium Phosphate

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