Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine

doi:10.3724/SP.J.1095.2014.30501

Chinese Journal of Applied Chemistry

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Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine

WU Shengfu¹, HUANG Runjun², CHEN Donglian², HUANG Zengwei³, MA Shaomei³, YUAN Aiqun^3*

(1.College of Preparatory Training Courses Education,Guangxi University For Nationalities,Nanning 530006,China;
2.Guilin University of Technology at Nanning,Nanning 530001,China;
3.College of Chemistry and Chemical Engineering,Guangxi University for Nationalities,Nanning 530006,China)

Received:2013-10-09 Revised:2014-01-02 Published:2014-07-10 Online:2014-07-10

Abstract

Abstract: The intercalation reaction between aluminum dihydrogen tripolyphosphate(ATP) and organic amine such as methylamine, ethylamine, propylamine and butylamine were characterized by infrared, X-ray diffraction, scanning electron microscopy, energy disperses spectroscopy as well as gravitational thermal analysis and titration experiment. The results show that the organic amine is intercalated into the interlayer of ATP. The interlayer spacing of ATP is extended from 0.795 nm to 1.71 nm by intercalation of organic amine. The interlayer spacing of the intercalation compound is linear to the carbon number(Cn) of organic amine with d=0.229Cn+0.811 and R2=0.9986. Long molecule chains result in stripping tendency of the intercalation compounds. The acidity and thermal decomposition temperature of ATP are also changed after the intercalation of organic amine, but all layered particle morphologies are similar.

Key words: aluminium dihydrogen triphosphate, organic amine, intercalation reaction, solid acid

CLC Number:

O611.3

WU Shengfu1, HUANG Runjun2, CHEN Donglian2, HUANG Zengwei3, MA Shaomei3, YUAN Aiqun3*. Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine[J]. Chinese Journal of Applied Chemistry, DOI: 10.3724/SP.J.1095.2014.30501.

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Characteristics of Intercalation Reaction Between Aluminum Dihydrogen Tripolyphosphate and Organic Amine

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