Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires

doi:10.3724/SP.J.1095.2011.00318

Chinese Journal of Applied Chemistry ›› 2011, Vol. 28 ›› Issue (02): 136-141.DOI: 10.3724/SP.J.1095.2011.00318

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Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires

LU Qi^1,2, WANG Xian-Hong^1*, WANG Fo-Song¹

(1.Key Laboratory of Polymer Ecomaterials,Changchun Institute of Applied
Chemistry,Chinese Academy of Sciences,Changchun 130022;
2.Graduate School of Chinese Academy of Sciences,Beijing)

Received:2010-05-28 Revised:2010-07-21 Published:2011-02-10 Online:2011-02-10

Abstract

Abstract:

Three novel ferrocene-based oligo(phenylene ethynylene)s molecular wires were prepared by the Sonogashira coupling reaction of 1,1′-diiodoferrocene with different acetylenic compounds. The structures of all the products were confirmed by 1H NMR, 13C NMR and MS. The electronic structures of these molecular wires were forecasted by a quantum chemistry calculation, which indicated that they might contain favorable charge transport properties due to their abnormal LUMO energy level continuous attenuation.

Key words: ferrocene, oligo(phenylene ethynylene)s, molecular wires

CLC Number:

O625.6

LU Qi1,2, WANG Xian-Hong1*, WANG Fo-Song1. Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires[J]. Chinese Journal of Applied Chemistry, 2011, 28(02): 136-141.

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Synthesis of Ferrocene-based Oligo(p-phenylene ethynylene)s Molecular Wires

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