Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (2): 92-94.

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Linear Polysiloxane with Pendant DB-18-C-6:Synthesis and Property of Ion Transport Improvement

Gong Shuling, Lu Xueran, Lu Xianming, Chen Yuanyin   

  1. Department of Chemistry, Wuhan University, Wuhan 430072
  • Received:1994-07-29 Revised:1994-10-31 Published:1995-04-10 Online:1995-04-10

Abstract: 3'-Allyldibenzo-18-crown-6,prepared from 3-allylcatechol and 1,2-bis(β-(β′-chloroethoxy)-ethoxy)benzene,was subjected to hydrosilylation by methyldichlorosiloxane,followed by polycondensation with hydroxy-terminated polydimethylsiloxane to give a linearpolysiloxane with pendant crown ether moieties.The transport properties of sodium,potas-sium,and ammonium salts throtigh a bulk liquid membrane system usiiig this polysiloxane asa carrier have been investigated.

Key words: rown ether, polysiloxaiie, ioiiophore, liquid membrane