Chinese Journal of Applied Chemistry ›› 1995, Vol. 0 ›› Issue (2): 101-103.
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Lin Xinxin1, W E Lindsell2
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Abstract: NaBH3CN-ZnCl2 was applied for the selective reduction deoxygenation of hydroxyland carbonyl groups in ferrocene derivatives under mild condition without affecting on thecarboxy groups.The molar ratio of B/Fe and Zn/Fe,as well as the solvents showed important influences on the deoxygenation.The possible intermediates were suggested.
Key words: sodium cyanoborohydrate, zink chloride, ferrocene derivative, selective reduction
Lin Xinxin, W E Lindsell. Selective Reduction of Oxygen-Containing Ferrocene Derivatives with NaBH3CN-ZnCl2[J]. Chinese Journal of Applied Chemistry, 1995, 0(2): 101-103.
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