Chinese Journal of Applied Chemistry ›› 1994, Vol. 0 ›› Issue (2): 96-98.

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Surface Modification by Fluorine and Oxygen-Nitrogen Permeability of Poiy[1-(trimethylsilyl)-1-propyne]

Qiu Xuepeng, Zheng Guodong, Xu Guanfan, Zhang Wenhao, Wen Jiumian, Zhang Jinlan, Xu Jiping   

  1. Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022
  • Received:1993-05-26 Revised:1993-10-28 Published:1994-04-10 Online:1994-04-10

Abstract: Poly[1-(trimethylsilyl)-1-propyne] membranes were modified with fluorine gas. The fluorinated membranes exhibited good gas permeation properties and a significant increase in gas selectivity over the unfluorinated PTMSP membranes.The oxygen-nitrogen separation coefficient αo2/N2 increased from 1.5 to 4.75,the oxygen permeation coefficients Po2 decreased from 8600 to 370 barrier, and the constancy of gas permeabitily of the membranes was improved.

Key words: polytrimethylsilylpropyne, modification by fluorine, oxygen nitrogen permeability