STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ)(BROMOSUBSTITUTED BENZO-15-CROWN-5)

Chinese Journal of Applied Chemistry ›› 1993, Vol. 0 ›› Issue (4): 89-91.

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STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ)(BROMOSUBSTITUTED BENZO-15-CROWN-5)

Dong Wenkui

Department of Environmental Engineering, Lanzhon Bailway Institute, 730070 Lanzhou

Received:1992-11-26 Revised:1993-04-06 Published:1993-08-10 Online:1993-08-10

Abstract

Abstract: In this paper, the two coordination compounds of copper perchlorate with 4′-bromo(or 4′,5′-dibromo)-benzo=15-crown-5 have been prepared in acetone medium, the composition of the new coordination compounds have been determined as Cu(ClO₄)₂·L·3H₂O(L=4′-bromobenzo-15-crown-5 or 4′, 5′-dibromo-benzo-15-crown-5), the IR, UV, TG-DTA,X-ray powder diffraction analysis and molar conductance of these coordination compounds have also been studied. It shows that coordination number of the coordination compounds is 9.

Key words: copper perchlorate, crown ether, coordination compound

Dong Wenkui. STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ)(BROMOSUBSTITUTED BENZO-15-CROWN-5)[J]. Chinese Journal of Applied Chemistry, 1993, 0(4): 89-91.

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STUDY ON THE COORDINATION COMPOUND OF Cu(Ⅱ)(BROMOSUBSTITUTED BENZO-15-CROWN-5)

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