CONDUCTIVE PROPERTY OF DIPHTHALOCYANINE ERBIUM

Chinese Journal of Applied Chemistry ›› 1992, Vol. 0 ›› Issue (6): 92-94.

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CONDUCTIVE PROPERTY OF DIPHTHALOCYANINE ERBIUM

Diao Guowang¹, Wang Fulin¹, Ni Jiazuan², Xie Yunfen², Wang Xiao ³

1. Department of Chemistry, Yangzhou Teacher's College, Yangzhou 225002;
2. ChangChun Institute of Applied Chemistry, Academia Sinica, Changchun;
3. Yangzhou Environmental Monitoring Central Station, Yangzhou

Received:1991-12-05 Revised:1992-03-27 Published:1992-12-10 Online:1992-12-10

Abstract

Abstract: Diphthalocyanine erbium complex has been proved to be of a sandwich structure by x-ray diffraction spectrum,and ultraviolet and infraed spectrophotometry. The volt-ampere curve and the risistivity-temperatrue curve under different atmosphere showed its activation energy(ΔE) was 0.278eV in vacuum and 0.274eV in oxygen. Under diffrent atmosphere, the resistivity is 1.16(H₂), 1.14(vaeuum),1.03(N₂), 0.88(air), 0.86(O₂)ΜΩcm. It is showed that the conductive property of [Pc₂Er]H is due to the extrinsic impurity conduction.

Key words: diphthalocyanine erbium, conductivity, organic semiconductor

Diao Guowang, Wang Fulin, Ni Jiazuan, Xie Yunfen, Wang Xiao . CONDUCTIVE PROPERTY OF DIPHTHALOCYANINE ERBIUM[J]. Chinese Journal of Applied Chemistry, 1992, 0(6): 92-94.

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