RAMAN SPECTROSCOPIC STUDY OF MOLECULAR CONFORMATIONS OF DECYLAMINE HYDROCHLORIDE

Chinese Journal of Applied Chemistry ›› 1991, Vol. 0 ›› Issue (1): 14-17.

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RAMAN SPECTROSCOPIC STUDY OF MOLECULAR CONFORMATIONS OF DECYLAMINE HYDROCHLORIDE

Wang Wei, Li Laiming, Xi Shiquan

Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022

Received:1990-01-16 Revised:1990-04-18 Published:1991-02-10 Online:1991-02-10

Abstract

Abstract: The Raman spectra of decylamine hydrochloride (DeACl) were measured in solid stateand in aqueous micellar solutions,and the concentration dependence of molecular conforma-tions was studied.The results showed that in crystalline state DeACl molecules exist inall-trans structure,while in aqueous micellar solutions exist in disorder structure with severalgauche isomers.The order degree of conformations of DeACl decreases with increase of theconcentration, temperature and presence of Pr³⁺ ions in the aqueous solution.

Key words: surfactant, decylamine hydrochlotide, molecular conformation, Raman spectrum

Wang Wei, Li Laiming, Xi Shiquan. RAMAN SPECTROSCOPIC STUDY OF MOLECULAR CONFORMATIONS OF DECYLAMINE HYDROCHLORIDE[J]. Chinese Journal of Applied Chemistry, 1991, 0(1): 14-17.

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RAMAN SPECTROSCOPIC STUDY OF MOLECULAR CONFORMATIONS OF DECYLAMINE HYDROCHLORIDE

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