Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (3): 39-32.

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STUDY ON THE LATENT ACCELERATOR FOR EPOXY RESIN Ⅱ.EFFECT OF THE ACCELERATOR ON PHYSICAL PROPERTIES OF CURED RESIN

Song Yongxian, Peng Xinsheng, Li Rongxian   

  1. Changchun Institute of Applied Chemistry, Academia Sinica, Changchun 130022
  • Received:1989-06-30 Revised:1989-10-26 Published:1990-06-10 Online:1990-06-10

Abstract: The effect of a novel latent accelerator, neodymium acetylacetonate(AD), on the properties of cured resin for bisphenol A epoxy resin(E-44)/Tung oil acid anhydride(TOA)systemis reported in this paper. Presence of AD decreased the gel time at 150℃ and increased theactivation energy with increasing amount of AD. The E-44/TOA/AD system displayed bet-ter storage stability at 40℃ than the control. The incorporation of AD into the epoxy resin caused an increase in the Tg values anddepressed the dielectric loss Tano at 130℃、155℃ of Nd ion-containin g epoxy. The mechanical properties were raised as compared with the control. It might be due to the specialelectron structure of rare-earth elements which makes the epoxy system having higher Tg owing to the higher crosslink density or more homogenoous network structure.

Key words: epoxy resin, latent accelerator, physical property