Chinese Journal of Applied Chemistry ›› 1990, Vol. 0 ›› Issue (1): 91-93.

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OSCILLOGRAPHIC POTENTIOMETRIC ACID-BASE TITRATION WITH POLYANILINE MODIFIED ELECTRODE Ⅰ.ACID-BASE TITRATION IN AQUEOUS SOLUTION

Hu Xiaoya, Leng Zongzhou   

  1. Department of Chemistry, Yangzhou Teachers'College, Yangzhou 225002
  • Received:1989-03-27 Revised:1989-05-17 Published:1990-02-10 Online:1990-02-10

Abstract: Using polyaniline modified electrode as an indicator electrode and calomel electrodeas a reference electrode, the oscillographic potentiometric acid-base titrations were per-formed successfully in aqueous solutions containing strong acids or bases, weak acids orbases, polyprotontic acids or mixtures of bases. In comparison with biplatinum acid-baseoscillo-potentiometric titration this method gives more distinct potential breaks and thestoichiometric point can be observed easily with good roproducibility.

Key words: oscillographic potentiometric titration, acid-base titration, polyaniline modified electrode