Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (6): 74-76.

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OSCILLOGRAPHIC INDICATION TECHNIQUE IN KINETICALLY CONTROLLED ANALYSIS Ⅰ.DETERMINATIONS OF REDUCING SUBSTANCES WITH KBrO3-KBr-HCl SYSTEM

Xu Weijian, Liu Yan, Gao Hong(H. Kao)   

  1. Department of Chemistry, Nanjing University
  • Received:1988-12-30 Revised:1989-06-26 Published:1989-12-10 Online:1989-12-10

Abstract: This paper reports the use of the oscillographic indication technique in the kinetic method of analysis.The product resulted from the kinetic reaction in KBrO3-KBr-HCl system is used as a titrant and the zero current oscillographic bipotentiometric titrationtechnique is used to indicate the end point. The results obtained with KBrO3-KBr-HCl system show that this method can be used to determine reducing substances such as As(Ⅲ),ascorbic acid,etc.and has a sensitivity about 10-6-10-7mol/dm3.This method is directly visible and rapid and needs only simple equipment.

Key words: Oscillographic indication technique, Oscillographic bipotentiometry Kinetic method of analysis