Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (4): 59-61.

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STUDY ON THE THERMODYNAMIC PROPERTIES OF ADDITIVE REACTION FOR Ni[CF3COCHC(C4H4S) =NCH2]2 WITH SOME FIVE-MEMBERED HETEROCYCLES BY GLC METHOD

Guo Boshu, Zhou Jingyu, Yao Yuangen, You Xiaozeng   

  1. Coordination Chemistry Institute, Nanjing University
  • Received:1988-07-19 Revised:1989-01-18 Published:1989-08-10 Online:1989-08-10

Abstract: The solubillty constants KoR of some five-membered heterocycles i.e. furan, thiopheneand pyrrole, the apparent equilibrium constants KR and the stability constants K1 of theseLewis bases with Lewis acid Ni [CF3COCHC(C4H4S)=NCH2]2 in squalane solution aredetermined by GLC method. The thermodynamic parameters are calculated with the relation -RlnK1~1/T. The results of the experiments have been analysed.

Key words: GLC, Aoid-base adduct reaction, Thermodynamic parameter