Chinese Journal of Applied Chemistry ›› 1989, Vol. 0 ›› Issue (3): 59-61.

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THE STUDY OF THIN LAYER SPECTROELECTRO-CHEMISTRY OF [Co(H2O)4(NCS)3](18-C-6) COMPLEX

Yu Zhangyu, Li Haiying, Li Chunying, Gu Dengping   

  1. Department of Chemistry, Hebei Normal University, Shijiazhuang
  • Received:1988-04-25 Revised:1988-07-04 Published:1989-06-10 Online:1989-06-10

Abstract: The reduction of the title complex on a micro golden grid electrode using thin layercyclic voltammetry and spectrcelectrochemistry techniques was studied. The results showedthat the transfer number of the first step reduction of Co(Ⅱ) was 1, and E0= -0.583V(vs SCE). A mechanisum was Proposed.

Key words: Thin layer spectroelectrochemistry, Crown ether compound, Electrochemical reduction