Chinese Journal of Applied Chemistry ›› 1988, Vol. 0 ›› Issue (4): 33-36.

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STUDY ON THE COMPLEX OF TETRAHYDRATED MANGANOUS CHLORIDE WITH BENZO-15-CROWN-5 ETHER

Jiang Haiying1, L? Yugang2, Guo Jiuru 3   

  1. 1. Weinan Teachers' College;
    2. Northwest University;
    3. Xi'an Jiaotong University
  • Received:1987-03-23 Revised:1988-01-29 Published:1988-08-10 Online:1988-08-10

Abstract: A solid complex of manganous chloride with benzo-15-crown-5 ether was prepared from absolute alcohol and acetone in a wide range of mole ratio of salt to crown ether. The unique stoichiometric complex formed has been characterized as 3MnCl2·2B15C5·4H2O by elemental analysis, gas chromatography,IR-spectra, UV-spectra, x-ray diffraction, thermo gravimetric and differential thermal analysis.Its solubilities in some organic solvents are reported in the paper.

Key words: Manganous chloride, Crown ether, Complex Prcperty