Chinese Journal of Applied Chemistry ›› 1987, Vol. 0 ›› Issue (5): 82-85.
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Li Yi, Xu Xiaolong, Zhu Limin, Liu Guozhi
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Abstract: A solution of Cp2NdCl-LiCl-THF was prepared successfully and conveniently. The solution can be used to synthesize bis(cyclopentadienyl) organolanthanoid derivatives. Cp2NdC3H5 was prepared from Cp2NdCl-LiCl-THF solution and C3H5Li(1:1)at-78℃.CpNd(C3H5)2·THF and Li [CpNd(C3H5)3]·2Dioxan were prepared from [Li(THF)2]2 (μ-Cl)4CpNd.THF and C3H2Li(1:2 and 1:3 respectively). The new compounds were characterized by elemental analysis, GC, MS and IR. The spectra of all three compounds show a band characteristic of η3-allyl moieties.
Li Yi, Xu Xiaolong, Zhu Limin, Liu Guozhi. SYNTHESIS OF CYCLOPENTADIENYL ALLYL COMPLEXES OF NEODYMIUM[J]. Chinese Journal of Applied Chemistry, 1987, 0(5): 82-85.
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