Chinese Journal of Applied Chemistry ›› 1986, Vol. 0 ›› Issue (6): 48-53.

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THE AVERAGE MOLECULAR WEIGHT IN A GIVEN INTERVAL OF WESSLAU DISTRIBUTION AND LANSING-KRAEMER DISTRIBUTION

Dai Yukun   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1985-08-16 Published:1986-12-10 Online:1986-12-10

Abstract: A formula for calculating M in a given interval of Wesslau distribution and Lansing-Kraemer distribution has been derived. It is impossible that the molecular weight of any polymer will distribute over the whole range of 0-∞, hencc a GPC curve always has two boundaries. Therefore a GPC curve should be treated as a normal distribution curve wih its side tails cut out. This paper has shown that three parame-ters (M0, β and UR ) are necessary for characterizing a normal GPC curve.The precision of M calculated from GPC curve by Wesslau function is discussed.