Abstract: The crystal of the title compound is triclinic with space group PI and a=11.949(6)Å, b=12.886(5)Å, c=11.557(6)Å, α=112.93(3)°, β=115.92(4)°, γ=82.41(4)°. Diffraction bata of 3739 independent reflections were collected on Nicolet XRD R3 four circle diffractometer using Mokα radiation. The crystal structure was solved by the heavy atom method and difference Fourier synthesis and refined by the block least square to a final R=0.113 based on 3019 unique reflections upon F₀≥ 3σ(F₀). the stru-cture analysis showed that the coordination of neodymium by oxygen atoms is eight-fold with a geometry of a slightly distorted square antiprism and average Nd-O bond length 2.453Å and O-Nd-O angle ranged from 69.3°to 147.4°