Chinese Journal of Applied Chemistry ›› 1986, Vol. 0 ›› Issue (2): 11-16.
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Mao Xi-an1, Shen Lianfang1, Gao Yuan2, Ni Jiazhan2
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Abstract: 1H, 17O and 35Cl NMR chemical shifts of rare earth aqueous solutions were studied.The hydration number and hydrate configuration determined were as follows:The hydra-tion number of Pr, Nd ions is 9 and their hydrate configurations are tricapped trigonal prismatic. The hydration number of Tb, Dy, Ho, Er, Tm, Yb ions is 8 and their hydrate configurations are square antiprismatic. The hyperfine coupling constant between 17O and 4f electrons of rare earth ions was also calculated.
Mao Xi-an, Shen Lianfang, Gao Yuan, Ni Jiazhan. NMR STUDY ON HYDRATION NUMBER AND HYDRATE CONFIGURATION OF RARE EARTH IONS[J]. Chinese Journal of Applied Chemistry, 1986, 0(2): 11-16.
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