Chinese Journal of Applied Chemistry ›› 1985, Vol. 0 ›› Issue (4): 16-19.

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CHAIN TRANSFER REACTIONS IN THE POLYMERIZATION OF BUTADIENE WITH RARE EARTH COORDINATION CATALYST

Ji Xianzhong, Pang Shufen, Li Yuliang, Ouyang Jun   

  1. Changchun Institute of Applied Chemistry, Academia Sinica
  • Received:1984-01-03 Revised:1985-05-14 Published:1985-12-10 Online:1985-12-10

Abstract: Chain transfer reactions exist in the polymerization of butadiene initiated with rare earth coordination catalyst.The effect of various factors on chain transfer reactions in the polymerization of butadiene in the presence of NdCl3·3i-PrOH-AlEt3 system at various temperatures was examined in detail.