Chinese Journal of Applied Chemistry ›› 1985, Vol. 0 ›› Issue (2): 47-51.
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Sun Tao, Yang Jihua, Pang Shufen, Ouyang Jun
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Abstract: The kinetics of butadiene polymerization with a soluble rare earth catalyst(Nd(OCt)3-HAl(i-Bu)2-CH2=CHCH2Cl) has been studied. The experimental results showed that the rate of polymerization is first order in both the concentrations of monomer and neodymium compound, but is 1/3 order in the concentration of diisobutyl aluminum hydride. The number of active center and the apparent activation energy and the propagation activation energy of butadiene polymerization were determined.
Sun Tao, Yang Jihua, Pang Shufen, Ouyang Jun. THE KINETICS OF POLYMERIZATION OF BUTADIENE WITH Nd(OCt)3-HAI(i-Bu)2-CH2=CHCH2CI SYSTEM[J]. Chinese Journal of Applied Chemistry, 1985, 0(2): 47-51.
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