Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon

doi:10.11944/j.issn.1000-0518.2016.11.160148

Chinese Journal of Applied Chemistry ›› 2016, Vol. 33 ›› Issue (11): 1340-1342.DOI: 10.11944/j.issn.1000-0518.2016.11.160148

• Communications • Previous Articles

Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon

WU Liqiong,HAO Lihua,KONG Fanhua,LI Xinheng()

State Key Laboratory for Oxo Synthesis and Selective Oxidation,Suzhou Research Institute of LICP,Lanzhou Institute of Chemical Physics(LICP),Chinese Academy of Sciences,Suzhou,Jiangsu 215123,China

Received:2016-04-11 Accepted:2016-06-08 Published:2016-11-01 Online:2016-11-01
Contact: LI Xinheng
Supported by:
Supported by Innovation Fund of Petro-China(No.2014D-5006-0505)

Abstract

Abstract:

Mesoporous carbon with monolithic structures were prepared using abandoned crab shells as a template. And then Fe₃O₄ nanoparticles inside those monolithic mesopores were synthesized by the confined in-situ synthetic strategy. The properties and structure of Fe₃O₄ nanoparticles on nesoporous narbon were characterized by scanning electronic microscopy(SEM), transmission electron microscope(TEM) and X-ray diffraction(XRD). The results show that the pores have a monolithic structure. The diameters of the pores are ca. 40~50 nm and their lengths are ca. 50 μm to 200 μm. The nanoparticles are proven to be Fe₃O₄ with 10 nm in diameter, which have good size monodispersity and are evenly distributed inside the pores. This method features simple and environmental benignity.

Key words: Fischer-Tropsch synthesis, nanocatalysis, iron oxide, porous carbon, monolithic structures

WU Liqiong, HAO Lihua, KONG Fanhua, LI Xinheng. Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon[J]. Chinese Journal of Applied Chemistry, 2016, 33(11): 1340-1342.

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Confined In-Situ Synthesis of Ferroferric Oxide Nanoparticles on Mesoporous Carbon

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