Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone

doi:10.11944/j.issn.1000-0518.2015.10.150061

Chinese Journal of Applied Chemistry ›› 2015, Vol. 32 ›› Issue (10): 1134-1138.DOI: 10.11944/j.issn.1000-0518.2015.10.150061

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Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone

SUN Jinyu,SHI Yufang,WANG Guilin,ZHAO Minggen

Department of Chemistry,Xinhhou Teachers University,Xinzhou,Shanxi 034000,China

Received:2015-02-09 Accepted:2015-05-29 Published:2015-10-10 Online:2015-10-10
Contact: ZHAO Minggen
Supported by:
Supported by the Key Discipline Project of Xinzhou Teachers University(No.XK201205)

Abstract

Abstract:

A new nonlinear optical(NLO) organic material, 1-(pyrene-1-yl)- 3-(4-dimethyl aminophenyl)acrylic ketone(PMAK), was synthesized and characterized with ¹H NMR, IR, MS and elemental analysis. Meanwhile, the three-order nonlinear optical property of PMAK was tested by the Nd:YAG powder laser technology and the relevant parameters were determined. Nanosecond results are as follows:the refractive index n₂=-3.5×10^-17 m²/W, the absorption coefficient β=7.0×10^-10 m/W, the polarization rate χ⁽³⁾=2.54×10^-11 esu, the molecular hyperpolarizability γ=3.44×10^-30 esu. Picosecond results are as follows:n₂=-2.8×10^-18 m²/W, β=8.3×10^-11 m/W, χ⁽³⁾=2.49×10^-12 esu, γ=3.33×10^-31 esu.

Key words: pyrene derivative, (pyrene-yl)-(dimethylaminophenyl)acrylic ketone, chalcone, nonlinear optical property

SUN Jinyu,SHI Yufang,WANG Guilin,ZHAO Minggen. Synthesis and Three-order Nonlinear Optical Property of Pyrenyl Chalcone[J]. Chinese Journal of Applied Chemistry, 2015, 32(10): 1134-1138.

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