应用化学 ›› 2023, Vol. 40 ›› Issue (7): 1004-1016.DOI: 10.19894/j.issn.1000-0518.220372
方晓芸1,2,3, 赵林毅1,2, 王磊1,2,4, 李菱志1,2, 俞洁5, 陆泉芳5, 李燕飞1,2()
收稿日期:
2022-11-15
接受日期:
2023-06-21
出版日期:
2023-07-01
发布日期:
2023-07-19
通讯作者:
李燕飞
基金资助:
Xiao-Yun FANG1,2,3, Lin-Yi ZHAO1,2, Lei WANG1,2,4, Lin-Zhi LI1,2, Jie YU5, Quan-Fang LU5, Yan-Fei LI1,2()
Received:
2022-11-15
Accepted:
2023-06-21
Published:
2023-07-01
Online:
2023-07-19
Contact:
Yan-Fei LI
About author:
19063487@qq.comSupported by:
摘要:
为了在理论上建立起一套完整、客观的性能评价方法,对硅丙乳液的颗粒尺寸、热稳定性、结构和形貌进行了表征,测定了乳液质量分数与其粘度、表面张力等关系。通过用硅丙乳液修复模拟起甲和酥碱的壁画,进一步验证乳液的性能。结果表明,硅丙乳液属于非晶态(无定形态)结构,乳胶粒子形貌接近球形,平均粒径为190 nm,颗粒无团聚现象,较小的粒径可以提高乳液的渗透能力; Si—O—Si键的引入有效提高了硅丙乳液的热稳定性和耐热老化性; 随着硅丙乳液质量分数的增大,表面张力下降,相对粘度升高; 硅丙乳液的机械稳定性、贮存稳定性、热稳定性和耐盐性较好。硅丙乳液在修复起甲、酥碱壁画后,分别循环20和12次老化,颜料层未发生显著差异,说明硅丙乳液可以作为一种性能优异的胶凝材料用于起甲、酥碱壁画的修复中。
中图分类号:
方晓芸, 赵林毅, 王磊, 李菱志, 俞洁, 陆泉芳, 李燕飞. 硅丙乳液的表征、性能及其在模拟病害壁画修复中的应用[J]. 应用化学, 2023, 40(7): 1004-1016.
Xiao-Yun FANG, Lin-Yi ZHAO, Lei WANG, Lin-Zhi LI, Jie YU, Quan-Fang LU, Yan-Fei LI. Characterization, Property and Application of Silicone Acrylic Emulsion as a Kind of Protection Material for Murals[J]. Chinese Journal of Applied Chemistry, 2023, 40(7): 1004-1016.
图3 硅丙乳液胶膜(a)和硅丙乳液-硫酸钠胶膜(b)的XRD图谱
Fig.3 The XRD patterns of adhesive film for the silicone acrylic emulsion (a) and silicone acrylic emulsion-Na2SO4 (b)
图5 硅丙乳液和硅丙乳液-硫酸钠冷冻干燥(A、C)和室温干燥(B、D)后的SEM图
Fig.5 SEM images of the silicone acrylic emulsion and the silicone acrylic emulsion-Na2SO4 freeze-dried (A, C) and dried at room temperature (B, D)
图6 硅丙乳液胶膜(a)和硅丙乳液-硫酸钠胶膜(b)吸水率随时间的变化
Fig.6 Water absorption of adhesive film for the silicone acrylic emulsion (a) and silicone acrylic emulsion-Na2SO4 (b) with time change
图7 硅丙乳液(a)和硅丙乳液-硫酸钠(b)乳液的pH值随质量分数的变化
Fig.7 The effect of nass fraction of the silicone acrylic emulsion (a) and silicone acrylic emulsion-Na2SO4 (b)on pH
图8 硅丙乳液(a)和硅丙乳液-硫酸钠(b)的电导率随硅丙乳液质量分数的变化
Fig.8 The change of conductivity of the silicone acrylic emulsion (a) and silicone acrylic emulsion-Na2SO4 (b) with different concentration
图9 不同温度下硅丙乳液在蒸馏水(A)和1%硫酸钠溶液(B)中表面张力随质量分数的变化以及硅丙乳液和硅丙乳液-硫酸钠乳液的质量分数对表面张力的影响(C)
Fig.9 The change of surface tension of the silicone acrylic emulsion (A) and silicone acrylic emulsion-Na2SO4 (B) with the different mass fraction in different temperature and the effect of concentration of the silicone acrylic emulsion and silicone acrylic emulsion-Na2SO4 on the surface tension(C)
图10 硅丙乳液(A)和硅丙乳液-硫酸钠(B)在不同温度下相对粘度随乳液质量分数的变化
Fig.10 The change of viscosity of the silicone acrylic emulsion (A) and silicone acrylic emulsion-Na2SO4 (B) with the different mass fraction in different temperature
图11 质量分数1%~3%的硅丙乳液冻融前(A)、后(B)和含有1%不同盐质量分数为1%硅丙乳液冻融前后对比图(C)
Fig.11 The photographs of 1%~3% silicone acrylic emulsion before (A) and after (B) freezing and thawing and silicone acrylic emulsion containing different salts (C) before and after freezing and thawing
图12 试块原貌(A)、模拟起甲试块(B)、质量分数2.5%硅丙加固后(C)和20个循环老化后(D)的照片
Fig.12 The photograph of simulated test block(A), simulated flaking mural test block(B), mass fraction 2.5% silicone acrylic emulsion repaired flaking mural(C) and aging 20 cycle of flaking mural(D)
图13 酥碱试块(A)和质量分数2.5%硅丙加固后(B)照片,质量分数2.5%硅丙加固后(C)和12个循环老化后(D)的形貌
Fig.13 Picture of plaster disruption murals(A) and murals repaired by mass fraction of 2.5% silicone acrylic emulsion (B), SEM images of murals repaired by by mass fraction of 2.5% silicone acrylic emulsion (C) and aged for 12 cycles (D)
1 | 兰德省. 胶结材料在彩绘类文物保护修复中的应用案例[J]. 遗产与保护研究, 2019(1): 117-121. |
LAN D S. Application of cementing materials in protection and restoration of painted cultural relics[J]. Res Her Preser, 2019(1): 117-121. | |
2 | 汪万福, 李最雄, 马赞峰, 等. 西藏文化古迹严重病害壁画保护修复加固技术[J]. 敦煌研究, 2005(4): 24-29. |
WANG W F, LI Z X, MA Z F, et al. Protection, restoration and reinforcement of seriously damaged frescoes in Tibetan cultural relics[J]. Dunhuang Res, 2005(4): 24-29. | |
3 | SU B M, ZHANG H B, ZHANG B J, et al. A scientific investigation of five polymeric materials used in the conservation of murals in Dunhuang Mogao Grottoes[J]. J Cult Herit, 2018, 31: 105-111. |
4 | 佘广为. 核壳结构硅丙乳液的研制及纳米改性研究[D]. 北京: 北京化工大学, 2003. |
SHE G W. Preparation of core-shell structure organosilicon modified acrylic composite emulsion and study on the nano-modification[D]. Beijing: Beijing University of Chemical Technology, 2003. | |
5 | 孙道兴, 仇汝臣, 马新启. 硅丙乳液的合成方法及性能研究[J]. 中国涂料, 2002(3): 31-34. |
SUN D X, CHOU R C, MA X Q. A study of the synthisis and performance of the silicone-acrylic emulsion[J]. China Coat, 2001(3): 31-34. | |
6 | 巨浩波, 吕生华, 孙婷, 等. 石墨烯和硅丙乳液复合材料的制备及性能[J]. 高分子材料科学与工程, 2014, 30(8): 144-149. |
JU H B, LV S H, SUN T, et al. Preparation and properties of graphene and silicone-acrylic emulsion composites[J]. Polym Mater: Sci Eng, 2014, 30(8): 144-149. | |
7 | 朱杨荣, 张继德, 杨欢, 等. 室温自交联杂化硅丙乳液的制备及表征[J]. 材料科学与工程学报, 2006, 24(2): 244-248. |
ZHU Y R, ZHANG J D, YANG H, et al. Synthesis and characterization of self-cross linking hybrid silicone-acrylate emulsion at ambient temperature[J]. J Mater Sci Eng, 2006, 24(2): 244-248. | |
8 | 马建中, 王华金, 鲍艳. 核壳型硅丙复合乳液的合成及其性能研究[J]. 精细化工, 2010, 27(2): 195-200. |
MA J Z, WANG H J, BAO Y. Study on synthesis and performance of core/shell silicon-acrylate compounding latex[J]. Fine Chem, 2010, 27(2): 195-200. | |
9 | 温振华, 张三平, 周婵, 等. 有机硅氧烷改性丙烯酸乳液合成及性能研究[J]. 涂料工业, 2011, 41(8): 61-63. |
WEN Z H, ZHANG S P, ZHOU C, et al. Synthesis and performance of siloxane modified acrylic emulsion[J]. Paint Coat Ind, 2011, 41(8): 61-63. | |
10 | 陈德铨, 王坚, 王晨. 高性能硅丙乳液研究进展[J]. 上海化工, 2001(14): 22-24. |
CHEN D Q, WANG J, WANG C. Advance in research of silicone-acrylate emulsion with high performance[J]. Shanghai Chem Ind, 2001(14): 22-24. | |
11 | 姜绪宝, 朱晓丽, 张召, 等. 聚硅氧烷-聚丙烯酸酯-聚氨酯三元复合乳液的制备与表征及其胶膜性能[J]. 化学学报, 2011, 69(9): 1115-1125. |
JIANG X B, ZHU X L, ZHANG Z, et al. Preparation of polysiloxane-polyacrylic-polyurethane tri-component hybrid latexes and properties of the latexes and their films[J]. Acta Chim Sin, 2011, 69(9): 115-1125. | |
12 | 苏伯民, 潘月雷, 尹建军, 等. 有机硅-丙烯酸酯共聚水乳液的制备研究[J]. 敦煌研究, 2011(6): 18-23. |
SU B M, PAN Y L, YIN J J, et al. A study on the preparation of copolymerization water emulsion of organic silicone-acrylate[J]. Dunhuang Res, 2011(6): 18-23. | |
13 | CARRETTI E, DEI L. Physicochemical characterization of acrylic polymeric resins coating porous materials of artistic interes[J]. Prog Org Coat, 2004, 49: 282-289. |
14 | 苏伯民, 张化冰, 蒋德强, 等. 3种常用壁画保护材料的力学性能和水汽透过性研究[J]. 涂料工业, 2015, 45(6): 51-55. |
SU B M, ZHANG H B, JIANG D Q, et al. Mechanical properties and water vapor permeability of three conservation materials for wall paintings[J]. Paint Coat Ind, 2015, 45(6): 51-55. | |
15 | HANNA S B, DINSMORE J K. Proceedings of a symposium organized by the courtauld institute of art and the getty conservation institute[C]. London: The Getty Conservation Institute, 1991: 77-86. |
16 | 苏伯民, 张化冰, 谈翔, 等. 高分子材料应用于莫高窟壁画保护的历史、现状与研究[J]. 敦煌研究, 2018(1): 80-84. |
SU B M, ZHANG H B, TAN X, et al. The history, research findings, and current condition of polymeric materials used in the conservation of murals in the Dunhuang Mogao Grottoes[J]. Dunhuang Res, 2018(1): 80-84. | |
17 | 王旭东, 段修业, 李最雄, 等. 西藏萨迦寺壁画修复现场试验研究[J]. 敦煌研究, 2005(4): 16-23. |
WANG X D, DUAN X Y, LI Z X, et al. Field testing study on conservation and restoration of Sajia Temple in Tibet[J]. Dunhuang Res, 2005(4): 16-23. | |
18 | 苏伯民, 蒋德强, 马想生, 等. 布达拉宫等处壁画起甲原因的初步分析和修复材料的筛选[J]. 敦煌研究, 2007(5): 39-44. |
SU B M, JLANG D Q, MA X S, et al. Peliminan analysis on flaking wall paintings in Tibetand selection of resoration material[J]. Dunhuang Res, 2007(5): 39 - 44. | |
19 | 苏伯民, 张化冰, 蒋德强, 等. 壁画保护材料纯丙乳液的性能表征[J]. 涂料工业, 2014, 44(2): 54-59. |
SU B M, ZHANG H B, JIANG D Q, et al. Study and characterization on properties of pure acrylic emulsion used as mural paintings conservation materials[J]. Paint Coat Ind, 2014, 44(2): 54-59. | |
20 | 汪万福, 苏伯民, 青木繁夫. 几种壁画修复材料物性指数的实验测试[J]. 敦煌研究, 2000(1): 87-94. |
WANG W F, SU B M, SHIGEO AOKI. Experimental test on physical property index of several mural restoration mateials[J]. Dunhuang Res, 2000(1): 87-94. | |
21 | 王永进, 于群力, 阎敏, 等. 北方地区寺庙、殿堂壁画可溶盐活动规律的实验室模拟研究[J]. 文物保护与考古科学, 2010, 22(3): 15-20. |
WANG Y J, YU Q L, YAN M, et al. Research on the mobility of soluble salte for north templemurals[J]. Sci Conserv Archaeol, 2010, 22(3): 15-20. | |
22 | 靳治良, 陈港泉, 钱玲, 等. 基于莫高窟成盐元素相关系探究壁画盐害作用机理[J]. 化学研究与应用, 2009, 21(4): 450-454. |
JIN Z L, CHEN G Q, QIAN L, et al. Study on the mechanism of salt damages on the mural paintings of mogao grottoes[J]. Chem Res Appl, 2009, 21(4): 450-454. | |
23 | 李燕飞, 赵林毅, 王磊, 等. 聚醋酸乙烯酯乳液的表征、性能及其在彩绘类文物保护中的应用[J]. 文物保护与考古科学, 2021, 33(4): 22-32. |
LI Y F, ZHAO L Y, WANG L, et al. Characterization, property and application of PVAc emulsion as a kind of conservation material for painted cultural relics[J]. Sci Conserv Archaeol, 2021, 33(4): 22-31. | |
24 | 李燕飞, 赵林毅, 方晓芸, 等. 彩绘类文物保护材料明胶的表征及性能[J]. 西北大学学报(自然科学版), 2021, 57(1): 70-76, 83. |
LI Y F, ZHAO L Y, FANG X Y, et al. Characterization and properties of gelatin as a kind characterization and properties of gelatin as a kind[J]. J Northwest Norm Univ (Nat Sci), 2021, 57(1): 70-76, 83. | |
25 | 吴跃焕. 木器涂料用高固含量苯乙烯-丙烯酸酯微乳液的合成及其机理研究[D]. 广州: 华南理工大学, 2003. |
WU Y H. Synthesis and mechanism of high solid-content styrene-acrylate microlatex for wood-paints[D]. Guangzhou: South China University of Technology, 2003. | |
26 | 黄娟萍, 李素芳, 李娇, 等. 水性环氧复合乳化剂的合成及性能[J]. 应用化学, 2014, 31(3): 256-261. |
HUANG J P, LI S F, LI J, et al. Synthesis and properties of waterborne epoxy composite emulsifier[J]. Chin J Appl Chem, 2014, 31(3): 256-261. | |
27 | 孙中新, 李继航, 李毅, 等. 硅丙乳液的结构表征及性能研究[J]. 化学建材, 2001(2): 21-24. |
SUN Z X, LI J H, LI Y, et al. Study of structural attribute and performance of silicone-acrylate emulsion[J]. J Chem Build Mater, 2001(2): 21-24. | |
28 | 龚兴宇, 解云川, 张乾, 等. 高硅烷含量硅丙复合乳液的性能及应用研究[J]. 涂料工业, 2002, 32(5): 6-9. |
GONG X Y, XIE Y C, ZHANG Q, et al. Study on properties and application of silicone acrylic composite lotion with high silane content[J]. Paint Coat Ind, 2002, 32(5): 6-9. | |
29 | 闫蔚, 曾柏淋, 王淑美, 等. 6种硫酸盐类矿物药中红外鉴别[J]. 中国实验方剂学杂志, 2015, 21(20): 63-66. |
YAN W, ZENG B L, WANG S M, et al. Comparison of sulfate mineral medicines by infrared spectrum[J]. Chin J Exp Tradit Med Form, 2015, 21(20): 63-66. | |
30 | 刘信胜, 刘伟区, 石红义, 等. 有机硅丙烯酸酯改性水性聚氨酯的合成与性能[J]. 精细化工, 2019, 36(6): 1241-1248. |
LIU X S, LIU W Q, SHI H Y, et al. Synthesis and properties of silicone acrylate modified waterborne polyurethane[J]. Fine Chem, 2019, 36(6): 1241-1248. | |
31 | 俞洁, 杨格格, 庞二牛, 等. 羧甲基纤维素/聚乙二醇/丙烯酸高吸水性复合材料的性能测试[J]. 精细化工, 2013, 30(12): 1353-1358. |
YU J, YANG G G, PANG E N, et al. Performance testing of carboxymethyl cellulose/poly(ethylene glycol)/acrylic acid superabsorbent composite[J]. Fine Chem, 2013, 30(12): 1353-1358. | |
32 | 苏伯民, 孙秀娟, 张化冰, 等. ZB-WB-S 砂岩加固材料的性质表征和加固作用的初步研究[J]. 敦煌研究, 2013(1): 7-12. |
SU B M, SUN X J, ZHANG H B, et al. A preliminary study on the characterization and consolidation effects of the sandstone consolidating material ZB-WB-S[J]. Dunhuang Res, 2013(1): 7-12. | |
33 | WANG W T, DING G D, JIANG T, et al. Facile one-pot synthesis of VxOy/C catalysts using sucrose for the direct hydroxylation of benzene to phenol[J]. Green Chem, 2013, 15(5): 1150-1154. |
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