应用化学 ›› 2018, Vol. 35 ›› Issue (8): 972-974.DOI: 10.11944/j.issn.1000-0518.2018.08.180138

• 研究简报 • 上一篇    

静电纺丝制备有机盐类非线性光学材料纳米纤维

平林军,刘秀,尚树芳,杨洲(),王冬,曹晖,何万里   

  1. 北京科技大学材料科学与工程学院 北京 100083
  • 收稿日期:2018-04-28 接受日期:2018-06-20 出版日期:2018-07-24 发布日期:2018-07-24
  • 通讯作者: 杨洲
  • 基金资助:
    国家自然科学基金项目(51673023)资助

Electrospinning Preparation of Organic Salt Nonlinear Optical Material Nanofibers

PING Linjun,LIU Xiu,SHANG Shufang,YANG Zhou(),WANG Dong,CAO Hui,HE Wanli   

  1. School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China
  • Received:2018-04-28 Accepted:2018-06-20 Published:2018-07-24 Online:2018-07-24
  • Contact: YANG Zhou
  • Supported by:
    Supported by the National Natural Science Foundation of China(No.51673023)

摘要:

采用静电纺丝技术制备的有机非线性光学材料纳米纤维可有效控制非线性光学材料的分子取向,其生色团可实现与有机单晶类似的优化排列结构,表现出了与纯生色团分子相近的宏观二阶非线性光学性质。 本文将有机盐类非线性光学材料掺杂在聚乙烯吡咯烷酮中制备出了具有各向异性结构且表面光滑、排列有序的纳米纤维薄膜,Kurtz非线性测试结果表明,随着薄膜厚度增加,其二次谐波信号强度成正比增大。

关键词: 有机非线性光学材料, 静电纺丝, 有序纳米纤维

Abstract:

The use of electrospinning technology to prepare organic nonlinear optical nanofibers can effectively control the molecular orientation of nonlinear optical materials, the chromophores can achieve optimized arrangement similar to that of the organic single crystal showing macroscopic second-order nonlinear optics similar to pure chromophore molecules quality. In this paper, nonlinear optical organic salts were doped in polyvinylpyrrolidone to prepare nanofiber films with anisotropic structure, smooth surface and orderly arrangement. Kurtz nonlinear tests reflect that the second harmonic signal intensities are enhanced in a proportional manner with the increase of film thickness.

Key words: organic nonlinearity optical materials, electrospinning, well-aligned nanofiber