双金属金属有机骨架材料的制备及性能研究进展

doi:10.11944/j.issn.1000-0518.2018.05.170243

摘要/Abstract

摘要：

金属有机骨架材料(MOFs)具有拓扑结构的多样性和丰富的比表面积,使其在催化和吸附领域具有潜在的应用价值。双金属MOFs具有两种金属中心,较之单金属MOFs具有更加多元的催化活性位点和吸附位点,因此吸附选择性、选择催化性以及结构稳定性等均得到了提升。本文就如何制备性能优异的双金属MOFs材料,以及这种材料的结构特点、性能提升和应用前景展开了概述。

关键词: 金属有机骨架材料(MOFs), 双金属结构, 一锅法, 金属取代

Abstract:

Metal-organic frameworks(MOFs) have the diversity of topological structure and rich surface area, which make it have potential application value in the field of catalysis and adsorption. Because of the bimetallic MOFs have two metal centers, it has higher catalytic activity sites and adsorption sites than the single metal MOFs. So the selectivity of adsorption, catalytic activity, and stability of structure have all been improved. In this review, the synthesis methods, structure properties, performance improvement and application prospects of bimetallic MOFs are summarized.

Key words: metal-organic frameworks, dual-metal structure, one-pot method, metal substitution

元宁,杜冰洁,贾晓霞,杨江峰,李晋平. 双金属金属有机骨架材料的制备及性能研究进展[J]. 应用化学, 2018, 35(5): 500-510.

YUAN Ning,DU Bingjie,JIA Xiaoxia,YANG Jiangfeng,LI Jinping. Research Progress in Preparation Technology and Application of Bimetal Metal-Organic Frameworks Materials[J]. Chinese Journal of Applied Chemistry, 2018, 35(5): 500-510.

参考文献

[1]	Furukawa H,Cordova K E,O'Keeffe M,et al. The Chemistry and Applications of Metal-Organic Frameworks[J]. Science,2013,341(6149):1230444.
[2]	Furukawa H,Müller U,Yaghi O M.“Heterogeneity Within Order” in Metal-Organic Frameworks[J]. Angew Chem Int Ed,2015,54(11):3417-3430.
[3]	James S L.Metal-Organic Frameworks[J]. Chem Soc Rev,2003,32(5):276-288.
[4]	Kitagawa S. Metal-Organic Frameworks(MOFs)[J]. Chem Soc Rev,2014,43(16):5415-5418.
[5]	Zhou H C,Long J R,Yaghi O M.Introduction to Metal-Organic Frameworks[J]. Chem Rev,2012,112(2):673-674.
[6]	He Y,Zhou W,Qian G,et al. Methane Storage in Metal-Organic Frameworks[J]. Chem Soc Rev,2014,43(16):5657-5678.
[7]	Liu J,Thallapally P K,McGrail B P,et al. Progress in Adsorption-Based CO2 Capture by Metal-Organic Frameworks[J]. Chem Soc Rev,2012,41(6):2308-2322.
[8]	CHAEMCHUEN S,ZHOU Kui,YAO Chen,et al. Alkali-Metal Tuning of Adsorption Sites in Metal Organic Frameworks MOF-5 for Carbon Dioxide/Methane Separation at Ambient Conditions[J]. Chinese J Appl Chem,2015,32(5):552-556(in Chinese). CHAEMCHUEN S,周奎,姚宸,等. 碱性金属修饰金属有机骨架材料MOF-5吸附位点及其常态下分离二氧化碳/甲烷的应用[J]. 应用化学,2015,32(5):552-556.
[9]	Wu H,Gong Q,Olson D H,et al. Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks[J]. Chem Rev,2012,112(2):836-868.
[10]	Li J R,Sculley J,Zhou H C.Metal-Organic Frameworks for Separations[J]. Chem Rev,2011,112(2):869-932.
[11]	Qiu S,Xue M,Zhu G.Metal-Organic Framework Membranes:From Synthesis to Separation Application[J]. Chem Soc Rev,2014,43(16):6116-6140.
[12]	Van de Voorde B,Bueken B,Denayer J,et al. Adsorptive Separation on Metal-Organic Frameworks in the Liquid Phase[J]. Chem Soc Rev,2014,43(16):5766-5788.
[13]	Hu Z,Deibert B J,Li J.Luminescent Metal-Organic Frameworks for Chemical Sensing and Explosive Detection[J]. Chem Soc Rev,2014,43(16):5815-5840.
[14]	McGrail B P,Thallapally P K,Blanchard J,et al. Metal-Organic Heat Carrier Nanofluids[J]. Nano Energy,2013,2(5):845-855.
[15]	Annapureddy H V,Nune S K,Motkuri R K,et al. A Combined Experimental and Computational Study on the Stability of Nanofluids Containing Metal Organic Frameworks[J]. J Phys Chem B,2015,119(29):8992-8999.
[16]	Dhakshinamoorthy A,Garcia H.Metal-Organic Frameworks as Solid Catalysts for the Synthesis of Nitrogen-Containing Heterocycles[J]. Chem Soc Rev,2014,43(16):5750-5765.
[17]	Liu J,Chen L,Cui H,et al. Applications of Metal Organic Frameworks in Heterogeneous Supramolecular Catalysis[J]. Chem Soc Rev,2014,43(16):6011-6061.
[18]	Zhang T,Lin W.Metal-Organic Frameworks for Artificial Photosynthesis and Photocatalysis[J]. Chem Soc Rev,2014,43(16):5982-5993.
[19]	Canivet J,Fateeva A,Guo Y,et al. Water Adsorption in MOFs:Fundamentals and Applications[J]. Chem Soc Rev,2014,43(16):5594-5617.
[20]	Barea E,Montoro C,Navarro J A.Toxic Gas Removal-Metal-Organic Frameworks for the Capture and Degradation of Toxic Gases and Vapours[J]. Chem Soc Rev,2014,43(16):5419-5430.
[21]	Jeon J W,Sharma R,Meduri P,et al. In Situ One-Step Synthesis of Hierarchical Nitrogen-Doped Porous Carbon for High-Performance Supercapacitors[J]. ACS Appl Mater Interfaces,2014,6(10):7214-7222.
[22]	ZHANG Zhuoming,YANG Jiangfeng WANG Yong,et al. Effect of Water Molecules on Structure and Properties of Metal-Organic Frameworks[J]. Chinese J Inorg Chem,2015,31(4):627-634(in Chinese). 张倬铭,杨江峰,王勇,等. 水分子对金属有机骨架材料结构及性能的影响[J]. 无机化学学报,2015,31(4):627-634.
[23]	Burrows A D.Mixed-Component Metal-Organic Frameworks(MC-MOFs):Enhancing Functionality Through Solid Solution Formation and Surface Modifications[J]. CrystEngComm,2011,13(11):3623-3642.
[24]	Han S S,Mendoza-Cortés J L,Goddard Ⅲ W A. Recent Advances on Simulation and Theory of Hydrogen Storage in Metal Organic Frameworks and Covalent Organic Frameworks[J]. Chem Soc Rev,2009,38(5):1460-1476.
[25]	Chun H,Dybtsev D N,Kim H,et al. Synthesis, X-ray Crystal Structures, and Gas Sorption Properties of Pillared Square Grid Nets Based on Paddle-Wheel Motifs:Implications for Hydrogen Storage in Porous Materials[J]. Chem-Eur J,2005,11(12):3521-3529.
[26]	Burrows A D,Frost C G,Mahon M F,et al. Post-Synthetic Modification of Tagged Metal-Organic Frameworks[J]. Angew Chem Int Ed,2008,47(44):8482-8486.
[27]	Wu T,Bu X,Zhang J,et al. New Zeolitic Imidazolate Frameworks:From Unprecedented Assembly of Cubic Clusters to Ordered Cooperative Organization of Complementary Ligands[J]. Chem Mater,2008,20(24):7377-7382.
[28]	Zhang W,Shi Y,Li C,et al. Synthesis of Bimetallic MOFs MIL-100(Fe-Mn) as an Efficient Catalyst for Selective Catalytic Reduction of NO(x) with NH3[J]. Catal Lett,2016,146(10):1956-1964.
[29]	Chen Y Z,Wang C,Wu Z Y,et al. From Bimetallic Metal-Organic Framework to Porous Carbon:High Surface Area and Multicomponent Active Dopants for Excellent Electrocatalysis[J]. Adv Mater,2015,27(34):5010-5016.
[30]	Zhai Q G,Bu X,Mao C,et al. An Ultra-Tunable Platform for Molecular Engineering of High-Performance Crystalline Porous Materials[J]. Nat Commun,2016,7:13645
[31]	Song X,Oh M,Lah M S.Hybrid Bimetallic Metal-Organic Frameworks:Modulation of the Framework Stability and Ultralarge CO2 Uptake Capacity[J]. Inorg Chem,2013,52(19):10869-10876.
[32]	Bajpai A,Chandrasekhar P,Govardhan S,et al. Single Crystal-to-Single Crystal Site-Selective Postsynthetic Metal Exchange in a Zn-MOF Based on Semi-Rigid Tricarboxylic Acid and Access to Bimetallic MOFs[J]. Chem-Eur J,2015,21(7):2759-2765.
[33]	Stock N,Biswas S.Synthesis of Metal-Organic Frameworks(MOFs):Routes to Various MOF Topologies, Morphologies, and Composites[J]. Chem Rev,2011,112(2):933-969.
[34]	Braga D,Giaffreda S L,Grepioni F,et al. Mechanochemical Preparation of Molecular and Supramolecular Organometallic Materials and Coordination Networks[J]. Dalton Trans,2006,(10):1249-1263.
[35]	Wang L J,Deng H,Furukawa H,et al. Synthesis and Characterization of Metal-Organic Framework-74 Containing 2, 4, 6, 8, and 10 Different Metals[J]. Inorg Chem,2014,53(12):5881-5883.
[36]	Ma S,Sun D,Ambrogio M,et al. Framework-Catenation Isomerism in Metal-Organic Frameworks and Its Impact on Hydrogen Uptake[J]. J Am Chem Soc,2007,129(7):1858-1859.
[37]	Ma S,Wang X S,Manis E S,et al. Metal-Organic Framework Based on a Trinickel Secondary Building Unit Exhibiting Gas-Sorption Hysteresis[J]. Inorg Chem,2007,46(9):3432-3434.
[38]	Kaur G,Rai R K,Tyagi D,et al. Room-Temperature Synthesis of Bimetallic Co-Zn Based Zeolitic Imidazolate Frameworks in Water for Enhanced CO2 and H2 Uptakes[J]. J Mater Chem A,2016,4(39):14932-14938.
[39]	LI Zhihua,LIU Hong,SONG Linyong,et al. Synthesis of Dual-Metal Functionalized MOF-74 and Its Adsorption Properties[J]. Chinese J Inorg Chem,2017,33(2):237-242(in Chinese). 李志华,刘鸿,宋凌勇,等. 双金属功能化的MOF-74合成及气体吸附性能[J]. 无机化学学报,2017,33(2):237-242.
[40]	Fu Y,Xu L,Shen H,et al. Tunable Catalytic Properties of Multi-Metal-Organic Frameworks for Aerobic Styrene Oxidation[J]. Chem Eng J,2016,299:135-141.
[41]	Zhai Q G,Bu X,Mao C,et al. Systematic and Dramatic Tuning on Gas Sorption Performance in Heterometallic Metal-Organic Frameworks[J]. J Am Chem Soc,2016,138(8):2524-2527.
[42]	Qi Y J,Zhao D,Li X X,et al. Indium-Based Heterometal-Organic Frameworks with Different Nanoscale Cages:Syntheses, Structures, and Gas Adsorption Properties[J]. Cryst Growth Des,2017,17(3):1159-1165.
[43]	Lalonde M,Bury W,Karagiaridi O,et al. Transmetalation:Routes to Metal Exchange within Metal-Organic Frameworks[J]. J Mater Chem A,2013,1(18):5453-5468.
[44]	Wang J H,Zhang Y,Li M,et al. Solvent-Assisted Metal Metathesis:A Highly Efficient and Versatile Route Towards Synthetically Demanding Chromium Metal-Organic Frameworks[J]. Angew Chem Int Ed,2017,129(23):6578-6582.
[45]	Kole G K,Vittal J J.Solid-State Reactivity and Structural Transformations Involving Coordination Polymers[J]. Chem Soc Rev,2013,42(4):1755-1775.
[46]	YANG Jiangfeng,LI Jinping,JIA Xiaoxia,,et al. Method for Preparing Double-Metal MOFs Material through Metal Replacement Aided by Steam:CN. Method for Preparing Double-Metal MOFs Material through Metal Replacement Aided by Steam:CN,201610794646.0[P],2016-12-14(in Chinese). 杨江峰,李晋平,贾晓霞,等. 蒸汽辅助金属置换制备双金属MOFs材料的方法:中国,CN201610794646.0[P],2016-12-14.
[47]	Denysenko D,Werner T,Grzywa M,et al. Reversible Gas-Phase Redox Processes Catalyzed by Co-Exchanged MFU-4l(arge)[J]. Chem Commun,2012,48(9):1236-1238.
[48]	Dinca M,Dailly A,Liu Y,et al. Hydrogen Storage in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites[J]. J Am Chem Soc,2006,128(51):16876-16883.
[48]	Wang X S,Chrzanowski M,Wojtas L,et al. Formation of a Metalloporphyrin-Based Nanoreactor by Postsynthetic Metal-Ion Exchange of a Polyhedral-Cage Containing a Metal-Metalloporphyrin Framework[J]. Chem-Eur J,2013,19(10):3297-3301.
[50]	Bradshaw D,Warren J E,Rosseinsky M J.Reversible Concerted Ligand Substitution at Alternating Metal Sites in an Extended Solid[J]. Science,2007,315(5814):977-980.
[51]	Han Y,Chilton N F,Li M,et al. Post-Synthetic Monovalent Central-Metal Exchange, Specific I2 Sensing, and Polymerization of a Catalytic [3 3] Grid of [C$u^{Ⅱ}_{5}$C$u^{Ⅰ}_{4}$L6]·(Ⅰ)2·13H2O[J]. Chem-Eur J,2013,19(20):6321-6328.
[52]	Kim M,Cahill J F,Fei H,et al. Postsynthetic Ligand and Cation Exchange in Robust Metal-Organic Frameworks[J]. J Am Chem Soc,2012,134(43):18082-18088.
[53]	Wang X J,Li P Z,Liu L,et al. Significant Gas Uptake Enhancement by Post-Exchange of Zinc(Ⅱ) with Copper(Ⅱ) Within a Metal-Organic Framework[J]. Chem Commun,2012,48(83):10286-10288.
[54]	Zou L,Feng D,Liu T F,et al. A Versatile Synthetic Rroute for the Preparation of Titanium Metal Organic Frameworks[J]. Chem Sci,2016,7(2):1063-1069.
[55]	Chen Y,Yang C,Wang X,et al. Vapor Phase Solvents Loaded in Zeolite as the Sustainable Medium for the Peparation of Cu-BTC and ZIF-8[J]. Chem Eng J,2017,313:179-186.
[56]	Kumar G,Gupta R.Molecularly Designed Architectures-The Metalloligand Way[J]. Chem Soc Rev,2013,42(24):9403-9453.
[57]	Falkowski J M,Wang C,Liu S,et al. Actuation of Asymmetric Cyclopropanation Catalysts:Reversible Single-Crystal to Single-Crystal Reduction of Metal-Organic Frameworks[J]. Angew Chem Int Ed,2011,123(37):8833-8837.
[58]	Xie Z,Ma L,deKrafft K E,et al. Porous Phosphorescent Coordination Polymers for Oxygen Sensing[J]. J Am Chem Soc,2009,132(3):922-923.
[59]	Kitaura R,Onoyama G,Sakamoto H,et al. Immobilization of a Metallo Schiff Base into a Microporous Coordination Polymer[J]. Angew Chem Int Ed,2004,116(20):2738-2741.
[60]	Chen B,Zhao X,Putkham A,et al. Surface Interactions and Quantum Kinetic Molecular Sieving for H2 and D2 Adsorption on a Mixed Metal-Organic Framework Mmaterial[J]. J Am Chem Soc,2008,130(20):6411-6423.
[61]	Feng D,Gu Z Y,Li J R,et al. Zirconium-Metalloporphyrin PCN-222:Mesoporous Metal Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts[J]. Angew Chem Int Ed,2012,124(41):10453-10456.
[62]	Morris W,Volosskiy B,Demir S,et al. Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal Organic Frameworks[J]. Inorg Chem,2012,51(12):6443-6445.
[63]	Chen Y,Hoang T,Ma S.Biomimetic Catalysis of a Porous Iron-Based Metal-Metalloporphyrin Framework[J]. Inorg Chem,2012,51(23):12600-12602.