硅氧烷官能化聚芳醚腈自组装膜的制备及其性能

doi:10.11944/j.issn.1000-0518.2016.02.150205

摘要/Abstract

摘要：

杂萘联苯聚芳醚腈通过水解、酰化及氨丙基三乙氧基硅烷改性后,合成了侧链含有硅氧烷官能团功能性聚芳醚树脂(PNAS)。采用红外、¹H NMR、固体²⁹Si NMR谱等技术手段对产物结构进行表征,用DSC、TGA和原子力显微镜测试了PNAS树脂的性能和自组装薄膜的表面形貌。结果表明,PNAS具有优异的耐热性,其玻璃化转变温度为329 ℃,热失重温度(T_5%)达到492 ℃。与短链分子自组装膜比较,PNAS自组装薄膜具有良好的减摩抗磨性能,当载荷为400 mN时,自组装薄膜的稳定摩擦系数达到0.07且在5 h内基本不变。

关键词: 聚芳醚腈, 自组装膜, 摩擦学性能, 润滑

Abstract:

A novel triethoxysilyl-functionalized poly(phthalazinone ether nitrile)(PNAS) was synthesized by hydrolysis, acylation and 3-aminopropyltriethoxysilance-functionalization, and characterized by FTIR, ²⁹Si NMR, DSC and TGA. The self-assembled polymer film was designed to serve as wear resistant coating for silicon surface. It has an excellent heat-resistance with a glass transition temperature and the temperature at which 5% mass loss at 329 ℃ and 492 ℃, respectively. The surface morphology of self-assembled film was studied by atomic force microscopy, while the friction performance was investigated using reciprocating friction tester. Comparing with the short chain self-assembled film, the friction coefficient of the prepared film is very low(about 0.07 at the loading of 400 nN), and the anti-wear behavior is good, with a lack of failure after sliding over 5 hours.

Key words: poly(aryl ether nitrile), self-assembled film, tribology, lubrication

靳奇峰, 姜冬月, 佟丽娜, 蹇锡高. 硅氧烷官能化聚芳醚腈自组装膜的制备及其性能[J]. 应用化学, 2016, 33(2): 169-174.

JIN Qifeng, JIANG Dongyue, TONG Lina, JIAN Xigao. Preparation and Properties of Triethoxysilane Functionalized Poly(phthalazinone ether nitrile) Self-Assembled Thin Films[J]. Chinese Journal of Applied Chemistry, 2016, 33(2): 169-174.

参考文献

[1]	Lafontan X,Pressecg F,Beaudoin F,et al.The Advent of MEMS in Space[J]. Microelectron Reliab,2003,43(7):1061-1083.
[2]	Komvopoulos K,Yan Y. A Fractal Analysis of Stiction in Micromechanical System[J]. J Tribol,1997,119(3):391-400.
[3]	ZHOU Zhidan,XU Leihua,LIU Jinlong,et al.Domestic and Foreign Development on Self-assembled Films[J]. Mater Rev,2011,25(10):77-80(in Chinese). 周志丹,徐磊华,刘金龙,等. 国内外自组装膜的研究进展[J]. 材料导报,2011,25(10):77-80.
[4]	Cheng Y,Zheng B,Chuang P,et al.Solvent Effects on Molecular Packing and Tribological Properties of Octadecyltrichloosilane Films on Silicon[J]. Langmuir,2010,26(11):8256-8261.
[5]	Gu Q,Cheng X. Tribological Behaviors of Self-assembled 3-Aminopropyltriethoxysilane Films on Silicon[J]. Curr Appl Phys,2008,8(5):583-588.
[6]	Bai T,Cheng X H. Investigation of the Tribological Behavior of 3-Mercaptopropyltrimethoxysilane Deposited on Silicon[J]. Wear, 2006,261(7/8):730-737.
[7]	SUN Zhiyong,CHENG Xianhua. Friction/Wear Behaviors of Rare Earth Treated Carbon Nanotubes/Amino Silane Self-asembled Composite Film on Silion Substrate[J]. Tribology,2011,31(2):156-160(in Chinese). 孙志永,程先华. 硅基表面稀土改性碳纳米管/氨基硅烷自组装复合膜的摩擦磨损性能[J]. 摩擦学学报,2011,31(2):156-160.
[8]	CHEN li. Micro-tribological Properties of Self-assembly Films on Amide-modified Surface[J]. Lubr Eng,2013,38(5):41-45(in Chinese). 陈丽. 氨基表面组装薄膜的构筑及其微观摩擦学特性[J]. 润滑与密封,2013,38(5):41-45.
[9]	ZHANG Huichen,GAO Yuzhou,LI Yabin,et al.Effects of Interfacial Contact Characteristics on the Friction Properties of Octadecyltrichorosilane and 3-Aminopropyltrimethoxysilane Self-assembled Monolayers[J]. Tribology,2004,24(1):6-10(in Chinese). 张会臣,高玉周,李亚斌,等. 界面接触特性对两种自组装分子膜摩擦特性的影响[J]. 摩擦学学报,2004,24(1):6-10.
[10]	Stouffer J M, McCarthy T J. Polymer Monolayers Prepared by the Spontaneous Adsorption of Sulfur- functionalized Polystyrene on Gold Surfaces[J]. Macromolecules,1988,21(5):1204-1208.
[11]	Lenk T J,Hallmark V M,Rabolt J F,et al.Formation and Characterization of Self-assembled Films of Sulfur-derivatized Poly(methyl methacrylates) on Gold[J]. Macromolecules,1993,26(6):1230-1237.
[12]	ZHOU Feng,LIU Weimin. Surface-initiated Polymerization on Inorganic Substrates and Its Use to the Fabrication of End-grafted Polymer Films[J]. Prog Chem,2002,14(2):141-145(in Chinese). 周峰,刘维民. 无机物表面引发聚合反应制备端接枝聚合物[J]. 化学进展,2002,14(2):141-145.
[13]	Zhao B,Brittain W J. Polymer Brushes: Surface-immobilized Macromolecules[J]. Prog Polym Sci,2000,25(5):677-710.
[14]	Jones R A L,Lehnert R J,Schonherr H,et al. Factors Affecting the Preparation of Permanently End-grafted Polystyrene Layers[J]. Polymer,1999,40(2):525-530.
[15]	Tran Y,Auroy P. Synthesis of Poly(styrene sulfonate) Brushes[J]. J Am Chem Soc,2001,123(16):3644-3654.
[16]	CUI Baofeng,ZHOU Huidi,ZHANG Junyan,et al.Preparation and Tribological Properties of Inserted PAMAM SAMs:Influence of Chain Length[J]. Tribology,2011,31(1):1-6(in Chinese). 崔宝凤,周惠娣,张俊彦,等. 聚酰胺胺类树枝形聚合物(PAMAM)插入式自组装膜的制备与摩擦学性能: 小分子链长的影响[J]. 摩擦学学报,2011,31(1):1-6.
[17]	JIAN Xigao,WANG Jinyan. Progresson High PerformanceEngineering Plastics Containing Phthalazinone Moieties and Their Applications[J]. Mater China,2012,31(2):16-23(in Chinese). 蹇锡高,王锦艳. 含二氮杂萘酮联苯结构高性能工程塑料研究进展[J]. 中国材料进展,2012,31(2):16-23.
[18]	WANG Mingjing. Study on Novel Poly(arylene ether nitrile)s Containing Phthalazinone Moieties[D]. Dalian:Dalian University of Technology,2007(in Chinese). 王明晶. 含二氮杂萘酮联苯结构新型聚芳醚腈的研究[D]. 大连:大连理工大学,2007.
[19]	ZU Yanhua,JIANG Pengbo,SONG Shuang,et al.Synthesis and Properties of Fluorine and Silicon Modified Polyurethane Self-assembly Films[J]. Chinese J Appl Chem,2012,29(10):1138-1142(in Chinese). 祖艳华,姜鹏波,宋爽,等. 氟硅改性聚氨酯自组装膜的合成及其性能[J]. 应用化学,2012,29(10):1138-1142.
[20]	Joseph R,Zhang S M,Ford W T. Structure and Dynamics of a Colloidal Silica-Poly(methyl methacrylate) Composite by 13C and 29Si MAS NMR Spectroscopy[J]. Macromolecules,1996,29(4):1305-1312.
[21]	Luzinov I,Julthongpiput D,Vinson A L,et al.Epoxy-Terminated Self-Assembled Monolayers: Molecular Glues for Polymer Layers[J]. Langmuir,2000,16(2):504-516.
[22]	XU Zhong,WANG Lei. Preparation and Tribological Behavior of a Self-assembled Film with Bionic Nonsmoothed Surface[J]. Surf Technol,2011,40(1):44-48(in Chinese). 徐中,王磊. 三维自组装膜的制备及其摩擦磨损试验[J]. 表面技术,2011,40(1):44-48.
[23]	WU Ju,CHENG Xianhua,SHANGGUAN Qianqian,et al.Preparation and Tribological Behavior of γ-Methacryloxypropyltriethoxysilane Self-assembled Monolayer on Glass Slide[J]. Tribology,2005,25(2):117-120(in Chinese). 吴炬,程先华,上官倩芡,等. γ-甲基丙烯酰氧丙基三甲氧基硅烷自组装膜的制备及其摩擦学性能[J]. 摩擦学学报,2005,25(2):117-120.