磁性纳米粒子负载钯催化剂在C—C键偶联反应中的应用

doi:10.11944/j.issn.1000-0518.2015.01.140078

摘要/Abstract

摘要：

磁性纳米粒子(MNPs)负载钯催化剂因具有高的催化活性及易于原位磁分离回收等优点而得到快速发展,成为一类具有广泛应用前景的纳米催化剂,在学术及工业领域均受到广泛的关注。本文对近年来MNPs负载钯催化剂在Suzuki、Heck等C—C偶联反应中的应用研究进行简要阐述,并对其发展前景进行了展望。

关键词: 磁性纳米粒子, 负载钯催化剂, C-C键偶联反应, Suzuki偶联反应, Heck偶联反应

Abstract:

Due to their high catalytic activity and easily recoverable characters, the magnetic nanoparitcles(MNPs) supported catalysts have received extensive attention in academy as well as industry. Thus, they have been developed into a kind of sustainable nanocatalysts with wide application prospect. In this paper, the recent development in the synthesis and application of MNPs supported palladium catalysts for a variety of C—C coupling reactions such as Suzuki coupling reactions, Heck coupling reactions, etc., is reviewed. A brief outlook of their developments is also presented.

Key words: magnetic nanoparticles, supported Pd catalysts, C-C coupling reaction, Suzuki coupling reaction, Heck coupling reaction

中图分类号:

O621.2

冯翠兰, 刘建平, 桂建舟, 刘澜涛. 磁性纳米粒子负载钯催化剂在C—C键偶联反应中的应用[J]. 应用化学, 2015, 32(1): 19-26.

FENG Cuilan, LIU Jianping, GUI Jianzhou, LIU Lantao. Application of Magnetic Nanoparticles Supported Pd Catalysts in C—C Bond Formation Reactions[J]. Chinese Journal of Applied Chemistry, 2015, 32(1): 19-26.

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